True or false · +4 / −1
Alcohols do not undergo elimination reactions.
Answer and solution
Answer: false
Solution
Chemistry ma’am · 4 steps
Heat ethanol with concentrated sulphuric acid and you get ethene: that is an elimination.
- What elimination means. In an elimination, a small molecule is removed from two neighbouring carbon atoms and a C=C double bond forms. For alcohols, the small molecule is water, so this reaction is called dehydration.
CH₃CH₂OH →(conc. H₂SO₄, 443 K) CH₂=CH₂ + H₂O
- How it happens. The acid protonates the -OH group, which then leaves as water. A carbocation forms, and it loses an H⁺ from the next carbon to give the alkene.
- Order of ease. Tertiary alcohols dehydrate most easily, because they form the most stable carbocation. The order is 3° > 2° > 1°. When more than one alkene can form, Saytzeff's rule picks the more substituted one as the major product.
- So. Alcohols do undergo elimination (dehydration to alkenes), so the statement is false.
The idea to keep. Alcohol plus a hot acid such as conc. H₂SO₄ or H₃PO₄ means elimination of water to give an alkene. Remember the ease of dehydration: 3° > 2° > 1°.
Answer from the NTA final answer key. Solution by PrepWiser.