JEE Main 2021 · 22 July · evening · Single correct · +4 / −1

The water having more dissolved O₂ is :

  1. (a) boiling water
  2. (b) water at 80°C
  3. (c) polluted water
  4. (d) water at 4°C
Answer and solution

Answer (d) water at 4°C

Solution

Chemistry ma’am · 3 steps

A gas dissolves best in cold, clean water, so pick the coldest and cleanest sample.

  1. Temperature effect. Dissolving O₂ in water releases heat, so heating drives the gas back out. The colder the water, the more oxygen it holds.
  2. Pollution effect. Polluted water carries organic waste. Microbes use up dissolved oxygen as they break that waste down, so the O₂ level falls and the BOD goes up.
    SampleWhat happens to dissolved O₂
    Boiling waterAlmost all of it is driven out
    Water at 80°CVery little left, since solubility is low when hot
    Polluted waterUsed up by microbes breaking down waste
    Water at 4°CHighest, because cold water holds the most gas
  3. So. Water at 4°C is the coldest, unpolluted sample, so it has the most dissolved oxygen. The answer is (d).

The idea to keep. The solubility of a gas in a liquid falls as temperature rises. Dissolved oxygen is also lowered by organic pollution, because microbes consume it.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 80 times in JEE Main since 2020. This question is from 2021.