Single correct · +4 / −1

Methanol can be prepared commercially by:

  1. (a) Fermentation of sugars
  2. (b) Catalytic hydration of ethene
  3. (c) Partial oxidation of natural gas
  4. (d) Reaction of Grignard reagent with formaldehyde
Answer and solution

Answer (c) Partial oxidation of natural gas

Solution

Chemistry ma’am · 3 steps

Methanol has just one carbon, so it comes from methane, the main part of natural gas.

  1. Count the carbons. Methanol, CH₃OH, has only one carbon atom. A commercial route needs a cheap one-carbon starting material, and natural gas is mostly methane, CH₄.
  2. Industrial route. Methane is partially oxidised (or steam-reformed) to synthesis gas, a mixture of CO and H₂. This gas is passed over a ZnO-Cr₂O₃ catalyst at about 573 to 673 K and 200 to 300 atm.

    CO + 2H₂ →(ZnO-Cr₂O₃, 573-673 K, 200-300 atm) CH₃OH

    OptionWhat it actually gives
    (a) Fermentation of sugarsEthanol, C₂H₅OH
    (b) Hydration of etheneEthanol, C₂H₅OH
    (c) Partial oxidation of natural gasMethanol, via CO + 2H₂
    (d) RMgX + HCHORCH₂OH, at least two carbons, and only a lab method
  3. So. Only (c) is a large-scale route to methanol: natural gas is partially oxidised, and the products are then turned into CH₃OH.

The idea to keep. For industrial alcohols, match the carbon count to a cheap feedstock. One carbon means methane or syngas (CO + 2H₂). Two carbons means ethene hydration or fermentation.

Answer from the NTA final answer key. Solution by PrepWiser.

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