Single correct · +4 / −1
Methanol can be prepared commercially by:
- (a) Fermentation of sugars
- (b) Catalytic hydration of ethene
- (c) Partial oxidation of natural gas
- (d) Reaction of Grignard reagent with formaldehyde
Answer and solution
Answer (c) Partial oxidation of natural gas
Solution
Chemistry ma’am · 3 steps
Methanol has just one carbon, so it comes from methane, the main part of natural gas.
- Count the carbons. Methanol, CH₃OH, has only one carbon atom. A commercial route needs a cheap one-carbon starting material, and natural gas is mostly methane, CH₄.
- Industrial route. Methane is partially oxidised (or steam-reformed) to synthesis gas, a mixture of CO and H₂. This gas is passed over a ZnO-Cr₂O₃ catalyst at about 573 to 673 K and 200 to 300 atm.
CO + 2H₂ →(ZnO-Cr₂O₃, 573-673 K, 200-300 atm) CH₃OH
Option What it actually gives (a) Fermentation of sugars Ethanol, C₂H₅OH (b) Hydration of ethene Ethanol, C₂H₅OH (c) Partial oxidation of natural gas Methanol, via CO + 2H₂ (d) RMgX + HCHO RCH₂OH, at least two carbons, and only a lab method - So. Only (c) is a large-scale route to methanol: natural gas is partially oxidised, and the products are then turned into CH₃OH.
The idea to keep. For industrial alcohols, match the carbon count to a cheap feedstock. One carbon means methane or syngas (CO + 2H₂). Two carbons means ethene hydration or fermentation.
Answer from the NTA final answer key. Solution by PrepWiser.