JEE Main 2021 · 24 February · evening · Single correct · +4 / −1

According to Bohr's atomic theory :
(A) Kinetic energy of electron is ∝ Z²/n².
(B) The product of velocity (v) of electron and principal quantum number (n), 'vn' ∝ Z².
(C) Frequency of revolution of electron in an orbit is ∝ Z³/n³.
(D) Coulombic force of attraction on the electron is ∝ Z³/n⁴.
Choose the most appropriate answer from the options given below :

  1. (a) (A), (C) and (D) only
  2. (b) (A) only
  3. (c) (C) only
  4. (d) (A) and (D) only
Answer and solution

Answer (d) (A) and (D) only

Solution

Chemistry ma’am · 3 steps

Write down how r and v depend on Z and n, and every other Bohr quantity follows from those two.

  1. The two basics. In Bohr's model the orbit radius is r ∝ n²/Z and the electron's speed is v ∝ Z/n. Build each statement from these.
    StatementBuild it from r and vResultVerdict
    (A) Kinetic energy1/2mv² ∝ (Z/n)²∝ Z²/n²correct
    (B) vnZ/n × n∝ Z, not Z²wrong
    (C) Frequencyv/(2π r) ∝ (Z/n)/(n²/Z)∝ Z²/n³, not Z³/n³wrong
    (D) Coulombic forcekZe²/r² ∝ Z × Z²/n⁴∝ Z³/n⁴correct
  2. Watch the extra Z. In the force, one Z comes from the nuclear charge Ze and two more come from 1/r². That is why the force has Z³.
  3. So. Only (A) and (D) are correct, which is option (d).

The idea to keep. Learn just two results by heart: r ∝ n²/Z and v ∝ Z/n. Energy, frequency, force and time period can all be built from these two in one line.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 170 times in JEE Main since 2020. This question is from 2021.