JEE Main 2021 · 26 February · morning · Single correct · +4 / −1

The orbital having two radial as well as two angular nodes is :

  1. (a) 3p
  2. (b) 5d
  3. (c) 4d
  4. (d) 4f
Answer and solution

Answer (b) 5d

Solution

Chemistry ma’am · 3 steps

Two angular nodes fixes l = 2, a d orbital; then use n - l - 1 to find which d has two radial nodes.

  1. Two node formulas. The number of angular nodes equals l. The number of radial nodes equals n - l - 1. Together they add up to n - 1 nodes in all.
  2. Angular nodes first. Two angular nodes means l = 2, so the orbital must be a d orbital. Then two radial nodes means n - 2 - 1 = 2, which gives n = 5.
    Orbitaln, lAngular nodes (l)Radial nodes (n - l - 1)
    3p3, 113 - 1 - 1 = 1
    5d5, 225 - 2 - 1 = 2
    4d4, 224 - 2 - 1 = 1
    4f4, 334 - 3 - 1 = 0
  3. So. Only 5d has two radial nodes and two angular nodes, so the answer is (b).

The idea to keep. Angular nodes come from l alone, and radial nodes are n - l - 1. Read off l from the angular nodes first, then use the radial count to find n.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 170 times in JEE Main since 2020. This question is from 2021.