JEE Main 2021 · 17 March · morning · Single correct · +4 / −1
If an electron is moving in the nᵗʰ orbit of the hydrogen atom, then its velocity (vₙ) for the nᵗʰ orbit is given as :
- (a) vₙ ∝ 1/n
- (b) vₙ ∝ n²
- (c) vₙ ∝ n
- (d) vₙ ∝ 1/n²
Answer and solution
Answer (a) vₙ ∝ 1/n
Solution
Physics sir · 3 steps
Combine the force balance with Bohr's quantisation rule, and r cancels to leave v in terms of n alone.
- Force balance. The Coulomb pull of the nucleus supplies the centripetal force: mv²/r = ke²/r². This gives mv² r = ke².
- Quantisation rule. Bohr's postulate fixes the angular momentum: mvr = nh/2π. Divide the first result by this one, and m and r both cancel.
vₙ = (2π k e²)/nh = e²/(2ε₀ n h)
- So. Everything except n is a constant, so vₙ ∝ 1/n. Numerically, vₙ = (2.19 × 10⁶)/n m s⁻¹ for hydrogen. The answer is (a).
The idea to keep. Remember the Bohr trio for hydrogen-like atoms: r ∝ n²/Z, v ∝ Z/n, E ∝ -Z²/n². Outer orbits are bigger and slower.
Answer from the NTA final answer key. Solution by PrepWiser.