JEE Main 2021 · 16 March · morning · Single correct · +4 / −1

The process that involves the removal of sulphur from the ores is :

  1. (a) Roasting
  2. (b) Smelting
  3. (c) Leaching
  4. (d) Refining
Answer and solution

Answer (a) Roasting

Solution

Chemistry ma’am · 2 steps

Sulphide ore plus air plus heat: the sulphur leaves as SO2 gas. That is roasting.

  1. Roasting. The sulphide ore is heated strongly in a regular supply of air, below its melting point. Sulphur is oxidised to SO₂ gas, which escapes, and the metal is left behind as its oxide.

    2ZnS + 3O₂ →(Δ) 2ZnO + 2SO₂ ↑

    ProcessWhat it does
    Roastingheats the ore in excess air; removes S (and As, Sb) as volatile oxides
    Smeltingreduces the oxide to molten metal; the flux removes gangue as slag
    Leachingdissolves the ore in a suitable solvent and leaves the gangue behind
    Refiningpurifies the crude metal after it has been extracted
  2. So. Removal of sulphur from ores is done by roasting, option (a).

The idea to keep. Sulphide ores are roasted, carbonate and hydrated ores are calcined. Both happen before reduction, because a metal oxide is far easier to reduce than a sulphide.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Metallurgy

Asked about 80 times in JEE Main since 2020. This question is from 2021.