JEE Main 2020 · 2 September · morning · Single correct · +4 / −1

While titrating dilute HCl solution with aqueous NaOH, which of the following will not be required?

  1. (a) Pipette and distilled water
  2. (b) Clamp and phenolphthalein
  3. (c) Burette and porcelain tile
  4. (d) Bunsen burner and measuring cylinder
Answer and solution

Answer (d) Bunsen burner and measuring cylinder

Solution

Chemistry ma’am · 3 steps

Picture the bench for an acid-base titration: nothing gets heated, and every volume is measured precisely.

  1. What the titration needs. A known volume of HCl goes into the flask, and NaOH is added from above until an indicator changes colour. The reaction HCl + NaOH → NaCl + H₂O is fast at room temperature.
    ItemJob in this titrationNeeded?
    Pipette, distilled waterPipette delivers an exact volume of HCl; water rinses the glasswareYes
    Clamp, phenolphthaleinClamp holds the burette upright; phenolphthalein shows the end point (colourless to pink)Yes
    Burette, porcelain tileBurette adds NaOH drop by drop; the white tile makes the faint pink easy to seeYes
    Bunsen burner, measuring cylinderNo heating is needed, and a measuring cylinder is too rough for titration volumesNo
  2. Why not heat. Heating is used only for slow reactions, such as KMnO₄ with oxalic acid at about 60 °C. Neutralisation of a strong acid by a strong base needs no burner.
  3. So. The pair that is not required is the Bunsen burner and measuring cylinder, option (d).

The idea to keep. In a titration, volumes are read from a pipette and burette, never a measuring cylinder. A burner appears only when the reaction is slow, as in the KMnO₄ and oxalic acid titration.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Ionic Equilibrium

Asked about 100 times in JEE Main since 2020. This question is from 2020.