JEE Main 2020 · 2 September · morning · Single correct · +4 / −1
While titrating dilute HCl solution with aqueous NaOH, which of the following will not be required?
- (a) Pipette and distilled water
- (b) Clamp and phenolphthalein
- (c) Burette and porcelain tile
- (d) Bunsen burner and measuring cylinder
Answer and solution
Answer (d) Bunsen burner and measuring cylinder
Solution
Chemistry ma’am · 3 steps
Picture the bench for an acid-base titration: nothing gets heated, and every volume is measured precisely.
- What the titration needs. A known volume of HCl goes into the flask, and NaOH is added from above until an indicator changes colour. The reaction HCl + NaOH → NaCl + H₂O is fast at room temperature.
Item Job in this titration Needed? Pipette, distilled water Pipette delivers an exact volume of HCl; water rinses the glassware Yes Clamp, phenolphthalein Clamp holds the burette upright; phenolphthalein shows the end point (colourless to pink) Yes Burette, porcelain tile Burette adds NaOH drop by drop; the white tile makes the faint pink easy to see Yes Bunsen burner, measuring cylinder No heating is needed, and a measuring cylinder is too rough for titration volumes No - Why not heat. Heating is used only for slow reactions, such as KMnO₄ with oxalic acid at about 60 °C. Neutralisation of a strong acid by a strong base needs no burner.
- So. The pair that is not required is the Bunsen burner and measuring cylinder, option (d).
The idea to keep. In a titration, volumes are read from a pipette and burette, never a measuring cylinder. A burner appears only when the reaction is slow, as in the KMnO₄ and oxalic acid titration.
Answer from the NTA final answer key. Solution by PrepWiser.