JEE Main 2021 · 24 February · morning · Single correct · +4 / −1

In the given figure, the energy levels of hydrogen atom have been shown along with some transitions marked A, B, C, D and E.
The transitions A, B and C respectively represent :

JEE Main PYQ figure
  1. (a) The series limit of Lyman series, second member of Balmer series and second member of Paschen series.
  2. (b) The ionization potential of hydrogen, second member of Balmer series and third member of Paschen series.
  3. (c) The series limit of Lyman series, third member of Balmer series and second member of Paschen series.
  4. (d) The first member of the Lyman series, third member of Balmer series and second member of Paschen series.
Answer and solution

Answer (c) The series limit of Lyman series, third member of Balmer series and second…

Solution

Physics sir · 3 steps

Read each arrow twice: the bottom level names the series, the gap to the top level gives the member number.

  1. Series from the bottom. The level an electron falls to fixes the series. Ending at n = 1 is Lyman, ending at n = 2 is Balmer, and ending at n = 3 is Paschen.
  2. Member from the gap. The first member comes from the level just above, the second from two levels above, and so on. So the member number is nᵤₚₚₑᵣ - n_(lower). A jump from the continuum (n = ∞, 0 eV) gives the series limit, the shortest wavelength of that series.
    TransitionFrom → toSeriesWhich line
    A∞ → 1Lymanseries limit
    B5 → 2Balmer5 - 2 = 3, third member
    C5 → 3Paschen5 - 3 = 2, second member
    D (for comparison)4 → 2Balmer4 - 2 = 2, second member
  3. So. A is the series limit of the Lyman series, B is the third member of the Balmer series and C is the second member of the Paschen series. That is option (c).

The idea to keep. Lower level gives the series, and nᵤₚₚₑᵣ - n_(lower) gives the member number. A fall from the continuum is always the series limit, never the first member.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 110 times in JEE Main since 2020. This question is from 2021.