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Hydrocarbons: Alkenes & Alkynes formula sheet

Every formula in the Hydrocarbons: Alkenes & Alkynes chapter for JEE Main, with one line on when it applies. Topic 1 is open to everyone; sign in free to read all 13 and download the PDF.

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Structure, stability and geometrical isomerism

Bonds and alkene stability
4× asked, last 2026
RX2C=CRX2>RX2C=CHR>RCH=CHR>RCH=CHX2>CHX2=CHX2\begin{aligned}&\ce{R2C=CR2}>\ce{R2C=CHR}>\ce{RCH=CHR}\\&\quad>\ce{RCH=CH2}>\ce{CH2=CH2}\end{aligned}
More alkyl: more hyperconjugation, smaller heat of hydrogenation; then trans > cis. C–C, C=C, C≡C: 154, 134, 120 pm.
Geometrical isomerism
3× asked, last 2026
abC=Cde: a≠b, d≠ebut-2-ene: μ cis 0.33 D, trans 0\begin{aligned}&\ce{abC=Cde}:\ a\ne b,\ d\ne e\\&\text{but-2-ene: }\mu\ \textit{cis}\ 0.33\ \text{D},\ \textit{trans}\ 0\end{aligned}
cis polar, boils higher (277 vs 274 K); trans packs better, melts higher. E: higher-priority groups apart.

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Practise Hydrocarbons: Alkenes & Alkynes

11 more formulas in 4 topics

Preparation of alkenes, Electrophilic addition to alkenes, Oxidation and ozonolysis and Alkynes. Read the first part free. Sign in free with Google to read the rest and download the PDF.

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Preparation of alkenes

  • Partial reduction of alkynes7×
  • Elimination6×

Electrophilic addition to alkenes

  • Addition of HX3×
  • Addition of halogens3×
  • Hydration

Oxidation and ozonolysis

  • H₂ uptake and unsaturation5×
  • KMnO₄6×
  • Ozonolysis15×

Alkynes

  • Preparation of alkynes4×
  • Acidity of terminal alkynes4×
  • Addition to alkynes3×

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Practise Hydrocarbons: Alkenes & Alkynes

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