JEE Main 2023 · 6 April · evening · Numerical answer · +4 / −0

Number of crystal systems from the following where body centred unit cell can be found, is ____________.
Cubic, tetragonal, orthorhombic, hexagonal, rhombohedral, monoclinic, triclinic

Answer and solution

Answer 3

Solution

Chemistry ma’am · 3 steps

Go through the 14 Bravais lattices and tick the systems that have a body-centred cell.

  1. What to check. There are 7 crystal systems but only 14 Bravais lattices. Not every system allows every centring (primitive, body-centred, face-centred, end-centred), so look up the allowed centrings for each system.
    Crystal systemAllowed unit cellsBody-centred?
    Cubicprimitive, body-centred, face-centredyes
    Tetragonalprimitive, body-centredyes
    Orthorhombicprimitive, body-centred, face-centred, end-centredyes
    Hexagonalprimitive onlyno
    Rhombohedralprimitive onlyno
    Monoclinicprimitive, end-centredno
    Triclinicprimitive onlyno
  2. Check the count. The cell counts add up to 3 + 2 + 4 + 1 + 1 + 2 + 1 = 14, which matches the 14 Bravais lattices.
  3. So. Only cubic, tetragonal and orthorhombic have a body-centred unit cell, so the answer is 3.

The common slip: 4. Counting monoclinic as body-centred gives 4. Monoclinic has only primitive and end-centred cells.

The idea to keep. Remember the 14 Bravais lattices as 3, 2, 4, 1, 1, 2, 1 across cubic, tetragonal, orthorhombic, hexagonal, rhombohedral, monoclinic, triclinic. Orthorhombic is the only one with all four centrings.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 40 times in JEE Main since 2020. This question is from 2023.