JEE Main 2022 · 25 July · morning · Single correct · +4 / −1
Melamine polymer is formed by the condensation of:
- (a)
- (b)
- (c)
- (d)
Answer and solution
Answer (a)
Solution
Chemistry ma’am · 4 steps
Melamine is a triazine: three ring nitrogens alternating with three carbons, each carbon carrying NH₂.
- Know the monomers. Melamine-formaldehyde resin forms when melamine condenses with formaldehyde, HCHO. All four options use HCHO, so the choice comes down to the amine.
- What melamine is. Melamine is 2,4,6-triamino-1,3,5-triazine, C₃H₆N₆. Its six-membered ring has three N atoms alternating with three C atoms, and each ring carbon carries one -NH₂ group.
Option Ring N atoms in ring NH₂ groups (a) 1,3,5-triazine 3 3 (b) pyrimidine 2 3 (c) benzene 0 3 (d) pyridine 1 2 - Condensation. The -NH₂ groups react with HCHO and lose water, building -NH-CH₂-NH⁻ links. Three amino groups per ring let the chains cross-link into a hard thermosetting network.
- So. Only (a) has the triazine ring with three amino groups, so melamine polymer comes from (a) with HCHO.
The idea to keep. Melamine resin = melamine + HCHO. Melamine is a six-membered ring of alternating C and N (three of each), with an NH₂ on every carbon. Count the ring nitrogens before you pick.
Answer from the NTA final answer key. Solution by PrepWiser.