JEE Main 2022 · 25 July · morning · Single correct · +4 / −1

Melamine polymer is formed by the condensation of:

  1. (a)
    Option (a)
  2. (b)
    Option (b)
  3. (c)
    Option (c)
  4. (d)
    Option (d)
Answer and solution

Answer (a)

Solution

Chemistry ma’am · 4 steps

Melamine is a triazine: three ring nitrogens alternating with three carbons, each carbon carrying NH₂.

  1. Know the monomers. Melamine-formaldehyde resin forms when melamine condenses with formaldehyde, HCHO. All four options use HCHO, so the choice comes down to the amine.
  2. What melamine is. Melamine is 2,4,6-triamino-1,3,5-triazine, C₃H₆N₆. Its six-membered ring has three N atoms alternating with three C atoms, and each ring carbon carries one -NH₂ group.
    OptionRingN atoms in ringNH₂ groups
    (a)1,3,5-triazine33
    (b)pyrimidine23
    (c)benzene03
    (d)pyridine12
  3. Condensation. The -NH₂ groups react with HCHO and lose water, building -NH-CH₂-NH⁻ links. Three amino groups per ring let the chains cross-link into a hard thermosetting network.
  4. So. Only (a) has the triazine ring with three amino groups, so melamine polymer comes from (a) with HCHO.

The idea to keep. Melamine resin = melamine + HCHO. Melamine is a six-membered ring of alternating C and N (three of each), with an NH₂ on every carbon. Count the ring nitrogens before you pick.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Polymers

Asked about 50 times in JEE Main since 2020. This question is from 2022.