JEE Main 2022 · 29 June · morning · Single correct · +4 / −1

The polymer, which can be stretched and remains its original status on releasing the force is

  1. (a) Bakelite.
  2. (b) Nylon 6, 6.
  3. (c) Buna-N.
  4. (d) Terylene.
Answer and solution

Answer (c) Buna-N.

Solution

Chemistry ma’am · 3 steps

Stretch it, let go, and it snaps back: that is an elastomer, and Buna-N is the only rubber here.

  1. What the property means. A polymer that stretches under force and returns to its shape when released is an elastomer. Its chains are held by the weakest intermolecular forces, so they can uncoil and recoil.
  2. Why it springs back. A few cross-links tie the coiled chains together. When the force is removed, these cross-links pull the chains back to their original positions.
    PolymerClass by intermolecular forcesBehaviour
    BakeliteThermosetting polymerRigid, heavily cross-linked, does not stretch
    Nylon 6,6FibreStrong hydrogen bonds, high tensile strength
    Buna-NElastomerStretches and returns to shape
    TeryleneFibreStrong dipole forces, chains packed tightly
  3. So. Buna-N, a synthetic rubber made from CH₂=CH-CH=CH₂ and acrylonitrile, is the elastomer. The answer is (c).

The idea to keep. Weakest forces with a few cross-links give elastomers (Buna-S, Buna-N, neoprene). Strong hydrogen bonds or dipole forces give fibres. A dense 3D network gives thermosets.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Polymers

Asked about 50 times in JEE Main since 2020. This question is from 2022.