JEE Main 2021 · 25 July · morning · Single correct · +4 / −1

Which one of the following chemical agent is not being used for dry-cleaning of clothes?

  1. (a) H₂O₂
  2. (b) CCl₄
  3. (c) Liquid CO₂
  4. (d) Cl₂C = CCl₂
Answer and solution

Answer (a) H₂O₂

Solution

Chemistry ma’am · 3 steps

Dry cleaning means cleaning without water, so look for the agent that is not a grease-dissolving solvent.

  1. What dry cleaning needs. Dry cleaning removes oily and greasy stains with a non-aqueous solvent instead of water. So every true dry-cleaning agent here must be a solvent that dissolves grease.
    AgentWhat it isRole in cleaning
    H₂O₂an oxidising agent, used as an aqueous solutionbleach in ordinary laundry, not a dry-cleaning solvent
    CCl₄chlorinated organic solventan early dry-cleaning solvent, now avoided because it is toxic
    Liquid CO₂non-polar solvent under pressurethe green dry-cleaning solvent, used with a suitable detergent
    Cl₂C=CCl₂tetrachloroethene (perchloroethylene)the classic dry-cleaning solvent
  2. Where H2O2 fits. H₂O₂ does not dissolve grease. It removes colour by oxidation, which is why green chemistry recommends it, with a catalyst, as a bleach for laundry in place of chlorine.
  3. So. The agent not used for dry cleaning is (a), H₂O₂.

The idea to keep. Dry-cleaning agents are grease-dissolving solvents: CCl₄, tetrachloroethene, and now liquid CO₂. H₂O₂ belongs to the bleaching list, not the solvent list.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 60 times in JEE Main since 2020. This question is from 2021.