JEE Main 2023 · 13 April · evening · Single correct · +4 / −1

What happens when methane undergoes combustion in systems A and B respectively?

JEE Main PYQ figure
  1. (a) System A | System B; Temperature falls | Temperature rises
    System ASystem B
    Temperature fallsTemperature rises
  2. (b) System A | System B; Temperature rises | Temperature remains same
    System ASystem B
    Temperature risesTemperature remains same
  3. (c) System A | System B; Temperature falls | Temperature remains same
    System ASystem B
    Temperature fallsTemperature remains same
  4. (d) System A | System B; Temperature remains same | Temperature rises
    System ASystem B
    Temperature remains sameTemperature rises
Answer and solution

Answer (b) System A | System B; Temperature rises | Temperature remains same

Solution

Chemistry ma’am · 4 steps

Combustion releases heat; ask where that heat can go: trapped in A, leaking out through the walls of B.

  1. Combustion is exothermic. Burning methane, CH₄ + 2O₂ → CO₂ + 2H₂O, releases heat. What happens to the temperature depends on whether the walls let that heat out.
    SystemWallsHeat exchangeTemperature
    AAdiabaticNone, q = 0; heat stays insideRises
    BDiathermicHeat flows out to the surroundingsRemains same
  2. System A. Adiabatic walls block heat flow. The energy released by combustion stays inside and warms the products, so the temperature rises.
  3. System B. Diathermic walls conduct heat. The released heat passes out to the surroundings until the system is back at their temperature, so its temperature stays the same.
  4. So. Temperature rises in A and remains the same in B, which is option (b).

The idea to keep. Adiabatic walls trap heat, so an exothermic change heats the system. Diathermic walls pass heat out, so the system stays at the temperature of its surroundings.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Chemical Thermodynamics

Asked about 160 times in JEE Main since 2020. This question is from 2023.