JEE Main 2023 · 31 January · morning · Single correct · +4 / −1
Adding surfactants in non polar solvent, the micelles structure will look like
- (a) d
- (b) a
- (c) c
- (d) b
Answer and solution
Answer (b) a
Solution
Chemistry ma’am · 4 steps
In an oily solvent the micelle turns inside out: polar heads hide in the centre and the tails face outward.
- Two-part molecule. A surfactant has a polar head that likes polar surroundings and a long non-polar hydrocarbon tail that likes non-polar surroundings.
- Like dissolves like. In a non-polar solvent, the tails mix happily with the solvent. The polar heads are the misfits, so they huddle together away from the solvent.
- Reverse micelle. Above the critical micelle concentration, the molecules form a sphere with all the polar heads packed at the core and the tails pointing out into the solvent. This is a reverse micelle, the opposite of a micelle in water.
Figure Heads Tails Verdict (a) clustered at the centre outward, into the solvent reverse micelle, correct (b) outward, facing the solvent pointing to the centre normal micelle, for water (c) in rows, exposed in rows no micelle formed (d) scattered, exposed scattered no micelle formed - So. The structure is figure (a), with heads inside and tails outside. That is option (b).
The idea to keep. The part of the surfactant that matches the solvent always faces the solvent. In water the tails hide inside; in a non-polar solvent the heads hide inside.
Answer from the NTA final answer key. Solution by PrepWiser.