True or false · +4 / −1

In complex nomenclature, "ammine" refers to ammonia as a ligand while "amino" refers to -NH₂ group.

Answer and solution

Answer: true

Solution

Chemistry ma’am · 3 steps

Watch the double m: ammine with two m's is the ammonia ligand, amino is the organic –NH₂ group.

  1. Ammine. Neutral NH₃ bonded to a metal through its lone pair is named ammine, spelled with a double m. For example, [Co(NH₃)₆]Cl₃ is hexaamminecobalt(III) chloride.
  2. Amino. Amino is the prefix for the -NH₂ group attached to carbon in organic compounds, as in 2-aminoethanoic acid (glycine). It has a single m and is a substituent name, not the name of the ammonia ligand.
    SpeciesNameWhere you meet it
    NH₃, neutralammineligand in a complex
    NH₂⁻, anionamidoanionic ligand in a complex
    -NH₂ on carbonaminosubstituent in organic compounds
  3. So. Ammine means the ammonia ligand and amino means the -NH₂ group, so the statement is true.

The idea to keep. For nitrogen names, check both the species and its charge. Neutral NH₃ ligand is ammine (double m), the anion NH₂⁻ is amido, and the organic -NH₂ group is amino.

Answer from the NTA final answer key. Solution by PrepWiser.

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