JEE Main 2023 · 6 April · morning · Numerical answer · +4 / −0

The radius of fifth orbit of the Li⁺⁺ is __________ × 10⁻¹² m.
Take: radius of hydrogen atom = 0.51 Aᵒ

Answer and solution

Answer 425

Solution

Physics sir · 4 steps

Bohr radius grows as n² and shrinks as Z: scale 0.51 Å by 25 and divide by 3.

  1. Bohr radius formula. For a hydrogen-like ion with one electron, the orbit radius is rₙ = r₀ n²/Z, where r₀ is the radius of the hydrogen atom in its ground state.
  2. Identify n and Z. Li⁺⁺ has lost two of its three electrons, so it is hydrogen-like with Z = 3. The fifth orbit means n = 5.

    r₅ = 0.51 Å × 5²/3 = 0.51 × 25/3 Å = 4.25 Å

  3. Convert units. 1 Å = 10⁻¹⁰ m = 100 × 10⁻¹² m, so 4.25 Å = 425 × 10⁻¹² m.
  4. So. The radius of the fifth orbit of Li⁺⁺ is 425 × 10⁻¹² m.

The common slip: 1275. Leaving out Z = 3 gives 0.51 × 25 = 12.75 Å, which is 1275, not 425. The extra protons in lithium pull the orbit inward.

The idea to keep. For any one-electron ion, r ∝ n²/Z. Higher orbit pushes the electron out, and a bigger nuclear charge pulls it in.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Atomic Physics

Asked about 110 times in JEE Main since 2020. This question is from 2023.