JEE Main 2023 · 11 April · evening · Single correct · +4 / −1
The energy of He⁺ ion in its first excited state is, (The ground state energy for the Hydrogen atom is -13.6 eV) :
- (a) -13.6 eV
- (b) -27.2 eV
- (c) -3.4 eV
- (d) -54.4 eV
Answer and solution
Answer (a) -13.6 eV
Solution
Physics sir · 4 steps
Use Eₙ = -13.6 Z²/n² with Z = 2 and n = 2: the Z² and the n² cancel each other.
- Hydrogen-like formula. He⁺ has a single electron, so the Bohr formula for hydrogen works with the nuclear charge Z included.
Eₙ = -13.6 Z²/n² eV
- Pick Z and n. Helium has Z = 2. The ground state is n = 1, so the first excited state is n = 2.
- Put in numbers. E₂ = -13.6 × 2²/2² = -13.6 × 4/4 = -13.6 eV.
- So. The energy of He⁺ in its first excited state is -13.6 eV, option (a).
The idea to keep. For any one-electron ion, energy goes as Z²/n². The first excited state means n = 2, not n = 1. Fix both numbers before you put anything into the formula.
Answer from the NTA final answer key. Solution by PrepWiser.