JEE Main 2023 · 25 January · evening · Single correct · +4 / −1
When the hydrogen ion concentration [H⁺] changes by a factor of 1000, the value of pH of the solution __________
- (a) decreases by 2 units
- (b) increases by 2 units
- (c) decreases by 3 units
- (d) increases by 1000 units
Answer and solution
Answer (c) decreases by 3 units
Solution
Chemistry ma’am · 3 steps
pH is a log scale, so a factor of 1000 in [H⁺] means log 1000 = 3 units of pH.
- Definition. pH = -log[H⁺]. Every factor of 10 in [H⁺] moves the pH by exactly 1 unit. The minus sign means more H⁺ gives a lower pH.
- Read the change. Here [H⁺] grows 1000 times, so the new value is 1000[H⁺]. A rise in [H⁺] is the reading that matches the options. A fall would raise the pH by 3, and no option says that.
pH_(new) = -log(1000[H⁺]) = -log 1000 - log[H⁺] = pH - 3
- So. Since 1000 = 10³, the pH decreases by 3 units, which is option (c).
The idea to keep. Count the powers of 10. If [H⁺] goes up 10ⁿ times, pH goes down by n. If [H⁺] goes down 10ⁿ times, pH goes up by n.
Answer from the NTA final answer key. Solution by PrepWiser.