JEE Main 2023 · 25 January · evening · Single correct · +4 / −1

When the hydrogen ion concentration [H⁺] changes by a factor of 1000, the value of pH of the solution __________

  1. (a) decreases by 2 units
  2. (b) increases by 2 units
  3. (c) decreases by 3 units
  4. (d) increases by 1000 units
Answer and solution

Answer (c) decreases by 3 units

Solution

Chemistry ma’am · 3 steps

pH is a log scale, so a factor of 1000 in [H⁺] means log 1000 = 3 units of pH.

  1. Definition. pH = -log[H⁺]. Every factor of 10 in [H⁺] moves the pH by exactly 1 unit. The minus sign means more H⁺ gives a lower pH.
  2. Read the change. Here [H⁺] grows 1000 times, so the new value is 1000[H⁺]. A rise in [H⁺] is the reading that matches the options. A fall would raise the pH by 3, and no option says that.

    pH_(new) = -log(1000[H⁺]) = -log 1000 - log[H⁺] = pH - 3

  3. So. Since 1000 = 10³, the pH decreases by 3 units, which is option (c).

The idea to keep. Count the powers of 10. If [H⁺] goes up 10ⁿ times, pH goes down by n. If [H⁺] goes down 10ⁿ times, pH goes up by n.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Ionic Equilibrium

Asked about 100 times in JEE Main since 2020. This question is from 2023.