JEE Main 2021 · 18 March · morning · Single correct · +4 / −1

A certain orbital has no angular nodes and two radial nodes. The orbital is :

  1. (a) 2s
  2. (b) 3s
  3. (c) 3p
  4. (d) 2p
Answer and solution

Answer (b) 3s

Solution

Chemistry ma’am · 4 steps

Angular nodes give you l, then radial nodes give you n. Read l first, then n.

  1. Two node formulas. An orbital has l angular nodes and n - l - 1 radial nodes. Together they make n - 1 nodes in all.
  2. Find l. No angular nodes means l = 0, so this is an s orbital. That already rules out 2p and 3p.
  3. Find n. Two radial nodes means n - 0 - 1 = 2, so n = 3.
    OrbitalAngular nodes (l)Radial nodes (n - l - 1)
    2s02 - 0 - 1 = 1
    3s03 - 0 - 1 = 2
    3p13 - 1 - 1 = 1
    2p12 - 1 - 1 = 0
  4. So. With n = 3 and l = 0, the orbital is 3s, which is option (b).

The idea to keep. Angular nodes equal l. Radial nodes equal n - l - 1. Get l from the angular count first, then use the radial count to find n.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Atomic Structure

Asked about 170 times in JEE Main since 2020. This question is from 2021.