JEE Main 2024 · 27 January · evening · Numerical answer · +4 / −1
Total number of ions from the following with noble gas configuration is _________.
Sr²⁺(z=38), Cs⁺(z=55), La²⁺(z=57), Pb²⁺(z=82), Yb²⁺(z=70) and Fe²⁺(z=26)
Answer and solution
Answer 2
Solution
Chemistry ma’am · 3 steps
Subtract the charge from Z and check whether the electron count lands exactly on 2, 10, 18, 36, 54 or 86.
- Count electrons. For a cation, electrons = Z - charge. An ion has a noble gas configuration only if this count equals a noble gas atomic number: 2, 10, 18, 36, 54 or 86.
Ion Electrons Configuration Noble gas? Sr²⁺ 38 - 2 = 36 [Kr] yes Cs⁺ 55 - 1 = 54 [Xe] yes La²⁺ 57 - 2 = 55 [Xe] 5d¹ no Pb²⁺ 82 - 2 = 80 [Xe] 4f¹⁴5d¹⁰6s² no Yb²⁺ 70 - 2 = 68 [Xe] 4f¹⁴ no Fe²⁺ 26 - 2 = 24 [Ar] 3d⁶ no - Filled is not noble. Yb²⁺ and Pb²⁺ have completely filled subshells, but they carry extra electrons beyond the noble gas core. A stable filled subshell does not make the configuration a noble gas configuration.
- So. Only Sr²⁺ and Cs⁺ match a noble gas, so the answer is 2.
The common slip: 3. Counting Yb²⁺ as noble gas because its 4f¹⁴ subshell is full gives 3, but 68 electrons is not a noble gas count.
The idea to keep. A noble gas configuration means the electron count equals a noble gas atomic number exactly. Filled d or f subshells on top of the core, as in Pb²⁺ or Yb²⁺, do not count.
Answer from the NTA final answer key. Solution by PrepWiser.