JEE Main 2025 · 3 April · morning · Single correct · +4 / −1

Match the LIST-I with LIST-II
Choose the correct answer from the options given below:

List - IList - II
A.₀¹ n+ ₉₂²³⁵ U → ₅₄¹⁴⁰ Xe+ ₃₈⁹⁴ Sr+2 ₀¹ nI.Chemical reaction
B.2 H₂+O₂ → 2 H₂ OII.Fusion with +ve Q value
C.₁² H+ ₁² H → ₂³ He+ ₀¹ nIII.Fission
D.₁¹ H+ ₁³ H → ₁² H+ ₁² HIV.Fusion with -ve Q value
  1. (a) A-II, B-I, C-III, D-IV
  2. (b) A-III, B-I, C-II, D-IV
  3. (c) A-III, B-I, C-IV, D-II
  4. (d) A-II, B-I, C-IV, D-III
Answer and solution

Answer (b) A-III, B-I, C-II, D-IV

Solution

Physics sir · 3 steps

Split a heavy nucleus or join light ones, then let binding energy decide the sign of Q.

  1. Sort by type. In A a neutron hits ²³⁵U and it breaks into two medium nuclei, so that is fission. In B only electrons rearrange between atoms and the nuclei stay unchanged, so that is a chemical reaction. C and D both combine light nuclei, so they are the two fusion entries.
  2. Sign of Q. Q is the total binding energy of the products minus that of the reactants. Use B(²H) ≈ 2.22 MeV, B(³H) ≈ 8.48 MeV and B(³He) ≈ 7.72 MeV. A free proton or neutron has zero binding energy.

    Q = Σ B_(products) - Σ B_(reactants)

    ReactionWhat happensQMatch
    A²³⁵U splits into Xe and Srlarge, positiveIII (fission)
    B2H₂ + O₂ → 2H₂O, nuclei unchangeda few eV onlyI (chemical)
    C²H + ²H → ³He + n7.72 - 4.45 = +3.27 MeVII (fusion, +ve Q)
    D¹H + ³H → 2 ²H4.45 - 8.48 = -4.03 MeVIV (fusion, −ve Q)
  3. So. The matching is A-III, B-I, C-II, D-IV, which is option (b). D has a negative Q because the tightly bound triton turns into two loosely bound deuterons.

The idea to keep. To find the sign of Q in a nuclear reaction, compare total binding energies. If the products are bound more tightly than the reactants, energy is released and Q is positive.

Answer from the NTA final answer key. Solution by PrepWiser.

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