Single correct · +4 / −1

The mean free path of a gas molecule depends on:

  1. (a) molecular diameter only
  2. (b) number density only
  3. (c) both molecular diameter and number density
  4. (d) neither
Answer and solution

Answer (c) both molecular diameter and number density

Solution

Physics sir · 3 steps

Picture one molecule sweeping out a cylinder: how fat it is and how crowded the gas is both matter.

  1. Collision cylinder. A molecule of diameter d hits any other molecule whose centre comes within d of its own. So as it moves a distance L, it sweeps out a cylinder of cross-section π d² and volume π d² L.
  2. Count the hits. With n molecules per unit volume, the number of collisions in that length is n π d² L. Allowing for the motion of the other molecules adds a factor √2.

    λ = 1/(√2 n π d²)

  3. So. λ falls as n rises and falls as d² rises, so it depends on both the molecular diameter and the number density. The answer is (c).

The idea to keep. Mean free path is distance per collision. Bigger molecules (larger d) or a more crowded gas (larger n) both mean more collisions, so λ ∝ 1/(n d²).

Answer from the NTA final answer key. Solution by PrepWiser.

Study Kinetic Theory of Gases

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