JEE Main 2021 · 24 February · morning · Single correct · +4 / −1

n mole of a perfect gas undergoes a cyclic process ABCA (see figure) consisting of the following processes.
A → B : Isothermal expansion at temperature T so that the volume is doubled from V₁ to V₂ = 2V₁ and pressure charges from P₁ to P₂
B → C : Isobaric compression at pressure P₂ to initial volume V₁.
C → A : Isochoric change leading to change of pressure from P₂ to P₁.
Total workdone in the complete cycle ABCA is :

JEE Main PYQ figure
  1. (a) nRTln 2
  2. (b) 0
  3. (c) nRT( ln 2 - 1/2 )
  4. (d) nRT( ln 2 + 1/2 )
Answer and solution

Answer (c) nRT( ln 2 - 1/2 )

Solution

Physics sir · 4 steps

Add up the work of the three legs one by one; the key is finding P₂V₁ from point B on the isotherm.

  1. Isothermal A to B. For an isothermal expansion, W_(AB) = nRT ln V₂/V₁ = nRT ln 2. It is positive because the gas expands.
  2. Isobaric B to C. At constant pressure, W_(BC) = P₂(V₁ - 2V₁) = -P₂V₁. Point B lies on the isotherm, so P₂(2V₁) = nRT, which gives P₂V₁ = nRT/2. So W_(BC) = -nRT/2, negative because the gas is compressed.
  3. Isochoric C to A. The volume does not change, so W_(CA) = 0.

    W_(cycle) = nRT ln 2 - nRT/2 + 0 = nRT(ln 2 - 1/2)

  4. So. The net work is nRT(ln 2 - 1/2), which is option (c). It is positive (0.693 > 0.5), as it should be for a cycle that runs clockwise on the P-V diagram.

The idea to keep. For a cycle, net work is the sum of the work in each leg. Use PV = nRT at a shared point to write unknown pressures in terms of nRT, and watch the sign of compression work.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Thermodynamics

Asked about 150 times in JEE Main since 2020. This question is from 2021.