PREPWISER.

Thermodynamics JEE Main PYQs PDF, 2020–2026

Thermodynamics has 150 questions in JEE Main papers from 2020 to 2026, about 21 per year across all shifts. The free PDF has 146 of them, each with its answer. The most asked topic is Thermodynamic Processes (68 questions), followed by First Law of Thermodynamics (30) and Carnot Engine (22).

Asked in JEE Main
1502020–2026, all shifts
In this free PDF
146with answers
Asked in 2026
19Latest paper: 2026 Apr S2
Most asked topic
Thermodynamic Processes68 Qs · 45% of the chapter
Difficulty mix
42% easy · 57% medium · 1% hardof the questions in the PDF

Answer key includedNo loginPractise online

Source: official NTA JEE Main papers · Updated

Practise these 146 questions free, no login Download PDF (0.6 MB)

13 of this chapter's questions came back in a later paper (2021–2026). See the most repeated.

How often it's asked in JEE Main

Thermodynamics had about 1 question per shift in recent JEE Main papers (2024–26). Most asked topic: Thermodynamic Processes. About 19 questions in the 2026 papers. (Some topics were cut in 2024; see what changed.)

It came up in most 2024–26 shifts in our bank (about 46 shifts). Question types in 2020–2026: about 119 MCQs and about 31 numerical.

How many questions from Thermodynamics in JEE Main, year by year

YearQuestionsPer shiftMCQNumerical
2026191.0136
2025221.2193
2024170.9170
2023220.9220
2022221.0157
2021321.22210
2020161.0115
2020–20261501.011931

Most asked Thermodynamics topics, 2020–2026

TopicQuestions
Thermodynamic Processes68
First Law of Thermodynamics30
Carnot Engine22
Work Done in Processes18
Heat Engines and Efficiency7

Every topic, year by year, is in the topic-wise table further down.

Counted from PrepWiser's question bank of JEE Main papers, 2020–2026. Per shift = questions that year ÷ shifts in our bank. Updated .

Download these numbers (CSV)

See all chapters' weightage →

Revise Thermodynamics before you practise

Two free sheets, made from the past JEE Main questions on this chapter.

Share card for Thermodynamics: JEE Main PYQs with answers, free PDF

Send this chapter to your study group

The link opens this page: the free PDF with 146 questions and answers, and online practice. Nobody needs to log in.

Thermodynamics questions per year

YearAskedIn PDF
20261916
20252222
20241717
20232222
20222222
20213232
20201615

in the free PDF asked, not in the PDFThe PDF only has questions we can print in full with a checked answer, so it holds 146 of the 150 asked.

Topic-wise weightage by year

How many Thermodynamics questions each topic had in every JEE Main year (all shifts), counting every question asked, including ones not in the PDF. Darker cells mean more questions.

TopicAskedShare2026202520242023202220212020
Thermodynamic Processes6845%1315985117
First Law of Thermodynamics3020%534756·
Carnot Engine2215%·1·4953
Work Done in Processes1812%·242352
Heat Engines and Efficiency75%1··1·32
Second Law and Entropy53%·1···22
All topics150100%19221722223216

Swipe the table sideways for older years.

Newest questions (2026)

The 12 newest of the 16 JEE Main 2026 Thermodynamics questions in the free PDF, latest shift first. The 2026 papers asked 19 in all.

  1. JEE Main 2026 · 8 Apr · Shift 2 · Thermodynamic Processes

    Initial pressure and volume of a monoatomic ideal gas are PP and VV. The change in internal energy of this gas in adiabatic expansion to volume Vfinal=27 VV_{{\text{final}}}=27{\ \mathrm{V}} is ____\_\_\_\_ J.

    Solve it online →
  2. JEE Main 2026 · 6 Apr · Shift 2 · Thermodynamic Processes

    A cylinder with adiabatic walls is closed at both ends and is divided into two compartments by a frictionless adiabatic piston. Ideal gas is filled in both (left and right) the compartments at same P,VP,V,

    T. Heating is started from left side until pressure changes to 27P/827{\mathrm{P}}/8. If initial volume of each compartment was 9 litres then the final volume in right-hand side compartment is ____\_\_\_\_ litres. (for this ideal gas CP/CV=1.5{\mathrm{C}}_{{{\mathrm{P}}}}/{\mathrm{C}}_{{{\mathrm{V}}}}=1.5 )

    Solve it online →
  3. JEE Main 2026 · 5 Apr · Shift 1 · First Law of Thermodynamics

    Consider the following statements:

    A. Zeroth law of thermodynamics gives concept of temperature

    B. First law of thermodynamics gives concept of internal energy

    C. In isothermal expansion of ideal gas, ΔQ≠ΔW\Delta Q\neq \Delta W

    D. Product of intensive and extensive variables is extensive

    E. The ratio of any extensive variable to mass will be an extensive variable

    Choose the correct combination of statements from the options given below:

    Solve it online →
  4. JEE Main 2026 · 5 Apr · Shift 1 · Thermodynamic Processes

    Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R{\mathbf{R}}

    Statement I : Change in internal energy of a system containing nn mole of ideal gas can be written as ΔU=nCv(Tf−Ti)=nRγ−1(Tf−Ti)\Delta{\mathrm{U}}=n{\mathrm{C}}_{v}(T_{{{\mathrm{f}}}}-T_{i})=\frac{nR}{\gamma-1}(T_{{{\mathrm{f}}}}-T_{i}), where γ=CpCv,Ti=\gamma=\frac{C_{p}}{C_{v}},T_{i}= initial temperature, Tf=T_{{{\mathrm{f}}}}= final temperature.

    Statement II : Relation between degree of freedom ff and γ(=Cp/Cv)\gamma(=C_{p}/C_{v}) is (γ=1+2f)\left(\gamma=1+\frac{2}{f}\right)

    Choose the correct answer from the options given below

    Solve it online →
  5. JEE Main 2026 · 2 Apr · Shift 1 · Thermodynamic Processes

    A vessel contains 0.15 m3 of a gas at pressure 8 bar and temperature 140 °C with cp=3Rc_{p}=3R and cv=2Rc_{v}=2R. It is expanded adiabatically till pressure falls to 1 bar. The work done during this process is _________ kJ. (R is gas constant)

    Solve it online →
  6. JEE Main 2026 · 2 Apr · Shift 1 · Thermodynamic Processes

    Heat is supplied to a diatomic gas at constant pressure. Then the ratio of ΔQ:ΔU:ΔW\Delta Q:\Delta U:\Delta W is ______.

    Solve it online →
  7. JEE Main 2026 · 2 Apr · Shift 2 · First Law of Thermodynamics

    5 moles of unknown gas is heated at constant volume from 10°C to 20°C. The molar specific heat of this gas at constant pressure cp=8c_{p}=8 cal/mol.°C and R=8.36R=8.36 J/mol.°C. The change in the internal energy of the gas is __________ calorie.

    Solve it online →
  8. JEE Main 2026 · 28 Jan · Shift 1 · Thermodynamic Processes

    In the following p−Vp-V diagram the equation of state along the curved path is given by (V−2)2=4ap(V-2)^{2}=4ap where aa is a constant. The total work done in the closed path is

    JEE Main PYQ figure
    Solve it online →
  9. JEE Main 2026 · 28 Jan · Shift 2 · Thermodynamic Processes

    A thermodynamic system is taken through the cyclic process ABC as shown in the figure. The total work done by the system during the cycle ABC is ______ J.

    JEE Main PYQ figure
    Solve it online →
  10. JEE Main 2026 · 24 Jan · Shift 2 · Thermodynamic Processes

    10 mole of an ideal gas is undergoing the process shown in the figure. The heat involved in the process from P1P_{1} to P2P_{2} is α\alpha Joule ( P1=21.7 PaP_{1}=21.7{\ \mathrm{Pa}} and P2=30 Pa,Cv=21 J/K.mol,R=8.3 J/mol.K)P_{2}=30{\ \mathrm{Pa}},{\mathrm{C}}_{v}=21{\ \mathrm{J}}/{\mathrm{K}}.{\mathrm{mol}},R=8.3{\ \mathrm{J}}/{\mathrm{mol}}.{\mathrm{K}}). The value of α\alpha is ____\_\_\_\_ .

    JEE Main PYQ figure
    Solve it online →
  11. JEE Main 2026 · 24 Jan · Shift 1 · First Law of Thermodynamics

    Density of water at 4∘C4^{{\circ}}{\mathrm{C}} and 20∘C{20}^{{\circ}}{\mathrm{C}} are 1000 kg/m31000{\ \mathrm{kg}}/{\mathrm{m}}^{3} and 998 kg/m3998{\ \mathrm{kg}}/{\mathrm{m}}^{3} respectively. The increase in internal energy of 4 kg of water when it is heated from 4∘C4^{{\circ}}{\mathrm{C}} to 20∘C{20}^{{\circ}}{\mathrm{C}} is ____\_\_\_\_ J.

    (specific heat capacity of water =4.2 J/kg=4.2{\ \mathrm{J}}/{\mathrm{kg}}. and 1 atmospheric pressure =105 Pa={10}^{5}{\ \mathrm{Pa}} )

    Solve it online →
  12. JEE Main 2026 · 23 Jan · Shift 2 · Thermodynamic Processes

    The internal energy of a monoatomic gas is 3nRT. One mole of helium is kept in a cylinder having internal cross section area of 17 cm217{\ \mathrm{cm}}^{2} and fitted with a light movable frictionless piston. The gas is heated slowly by suppling 126 J heat. If the temperature rises by 4∘C4^{{\circ}}{\mathrm{C}}, then the piston will move ____\_\_\_\_ cm.

    (atmospheric pressure =105 Pa={10}^{5}{\ \mathrm{Pa}} )

    Solve it online →

Practise the 2026 Thermodynamics questions online

Sample questions from recent papers

JEE Main 2025 · 7 Apr · Shift 1 · Work Done in Processes

An ideal gas has undergone through the cyclic process as shown in the figure. Work done by the gas in the entire cycle is ________ ×10−1 J\times 10^{-1} \mathrm{~J}. (Take π=3.14\pi=3.14 )

JEE Main PYQ figure

Show answerHide answer

Answer: 314

Solve online

JEE Main 2025 · 28 Jan · Shift 1 · Carnot Engine

A Carnot engine (E)(\mathrm{E}) is working between two temperatures 473 K and 273 K . In a new system two engines - engine E1E_1 works between 473 K to 373 K and engine E2E_2 works between 373 K to 273 K . If η12,η1\eta_{12}, \eta_1 and η2\eta_2 are the efficiencies of the engines E,E1E, E_1 and E2E_2, respectively, then

  1. (A)η12=η1η2\eta_{12}=\eta_1 \eta_2
  2. (B)η12=η1+η2\eta_{12}=\eta_1+\eta_2
  3. (C)η12≥η1+η2\eta_{12} \geq \eta_1+\eta_2
  4. (D)η12<η1+η2\eta_{12}<\eta_1+\eta_2
Show answerHide answer

Answer: (D)

Solve online

JEE Main 2025 · 23 Jan · Shift 2 · Second Law and Entropy

Water of mass mm gram is slowly heated to increase the temperature from T1T_1 to TγT_\gamma. The change in entropy of the water, given specific heat of water is 1Jkg−1 K−11 \mathrm{Jkg}^{-1} \mathrm{~K}^{-1}, is :

  1. (A)m(T2−T1)\mathrm{m}\left(\mathrm{T}_2-\mathrm{T}_1\right)
  2. (B)zero
  3. (C)mln⁡(T1 T2)\mathrm{m} \ln \left(\frac{\mathrm{T}_1}{\mathrm{~T}_2}\right)
  4. (D)mln⁡(T2 T1)\mathrm{m} \ln \left(\frac{\mathrm{T}_2}{\mathrm{~T}_1}\right)
Show answerHide answer

Answer: (D)

Solve online

JEE Main 2023 · 30 Jan · Shift 2 · Heat Engines and Efficiency

Given below are two statements: one is labelled as Assertion A\mathbf{A} and the other is labelled as Reason R\mathbf{R}

Assertion A: Efficiency of a reversible heat engine will be highest at −273∘C-273^{\circ} \mathrm{C} temperature of cold reservoir.

Reason R: The efficiency of Carnot's engine depends not only on the temperature of the cold reservoir but it depends on the temperature of the hot reservoir too and is given as η=(1−T2T1)\eta=\left(1-\frac{T_{2}}{T_{1}}\right)

In the light of the above statements, choose the correct answer from the options given below
  1. (A)Both A\mathbf{A} and R\mathbf{R} are true and R\mathbf{R} is the correct explanation of A\mathbf{A}
  2. (B)Both A\mathbf{A} and R\mathbf{R} are true but R\mathbf{R} is NOT the correct explanation of A\mathbf{A}
  3. (C)A is false but R\mathbf{R} is true
  4. (D)A is true but R\mathbf{R} is false
Show answerHide answer

Answer: (A)

Solve online

The free PDF above has all 146 questions grouped by topic, with an answer key.

Practise these online, free, no login

Answer Thermodynamics PYQs in the browser, get each one checked instantly and open the step-by-step solution where there is one.

Practise Thermodynamics online

Frequently asked

How many questions come from Thermodynamics in JEE Main?

150 questions from 2020 to 2026, about 21 per year. In 2026 it had 19. The free PDF has 146 of them.

Which Thermodynamics topics are most important for JEE Main?

By past papers: Thermodynamic Processes (45%), First Law of Thermodynamics (20%) and Carnot Engine (15%) of all Thermodynamics questions.

Is the Thermodynamics PYQ PDF free?

Yes. The PDF and its answer key are free, and you can practise the questions online with no login, with step-by-step solutions where available.

More Physics chapters

JEE Main PYQs by year: 2026 · 2025 · 2024 · 2023 · 2022 · 2021 · 2020

Answers follow NTA's final answer keys. Typing errors are possible, so check doubtful answers against the official key. Spotted a mistake? prepwiser.in/feedback · Terms: prepwiser.in/terms