JEE Main 2022 · 27 July · morning · Single correct · +4 / −1

Which of the following methods are not used to refine any metal?
A. Liquation
B. Calcination
C. Electrolysis
D. Leaching
E. Distillation
Choose the correct answer from the options given below:

  1. (a) B and D only
  2. (b) A, B, D and E only
  3. (c) B, D and E only
  4. (d) A, C and E only
Answer and solution

Answer (a) B and D only

Solution

Chemistry ma’am · 3 steps

Ask what each method acts on: refining needs crude metal, but calcination and leaching only handle ore.

  1. What refining means. Refining is the last step of metallurgy. It takes an impure (crude) metal and removes the remaining impurities. A method counts as refining only if it acts on the metal itself.
    MethodWhat it acts onExampleRefining?
    A. LiquationCrude metal with a low melting pointSn, Pb, Bi melt and flow away from infusible impuritiesYes
    B. CalcinationConcentrated oreZnCO₃ → ZnO + CO₂ on heatingNo
    C. ElectrolysisCrude metal used as the anodeCu, Zn: pure metal deposits on the cathodeYes
    D. LeachingOre, dissolved in a reagentBauxite in NaOH, Ag and Au in NaCNNo
    E. DistillationCrude metal with a low boiling pointZn, Hg boil off and leave impurities behindYes
  2. Ore-stage methods. Leaching is a way of concentrating the ore. Calcination turns the concentrated ore into an oxide before reduction. Both happen before any metal has been produced, so they cannot refine a metal.
  3. So. Only calcination (B) and leaching (D) are not refining methods. The answer is (a).

The idea to keep. Sort each method by its stage: concentration (leaching, froth flotation), conversion to oxide (calcination, roasting), reduction, then refining. Only methods that act on crude metal count as refining.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 80 times in JEE Main since 2020. This question is from 2022.