JEE Main 2025 · 4 April · morning · Single correct · +4 / −1

X Y is the membrane/partition between two chambers 1 and 2 containing sugar solutions of concentration c₁ and c₂(c₁>c₂) mol L⁻¹. For the reverse osmosis to take place identify the correct condition.
(Here p₁ and p₂ are pressures applied on chamber 1 and 2 ).
A. Membrane/Partition : Cellophane, p₁>π
B. Membrane/Partition : Porous, p₂>π
C. Membrane/Partition : Parchment paper, p₁>π
D. Membrane/Partition : Cellophane, p₂>π
Choose the correct answer from the option given below:

JEE Main PYQ figure
  1. (a) A and C Only
  2. (b) A and D Only
  3. (c) B and D Only
  4. (d) C Only
Answer and solution

Answer (a) A and C Only

Solution

Chemistry ma’am · 3 steps

Reverse osmosis needs a semipermeable wall and extra pressure on the concentrated side, here chamber 1.

  1. Normal direction. Since c₁ > c₂, solvent naturally flows from chamber 2 (dilute) into chamber 1 (concentrated). The pressure that just stops this flow is the osmotic pressure π. For sugar, which does not ionise, it equals (c₁ - c₂)RT.
  2. Two conditions. To reverse the flow, push on the concentrated side with p₁ > π. The partition must also be semipermeable, letting solvent through but not sugar. Cellophane and parchment paper are semipermeable. A porous partition lets sugar pass as well, so no osmosis of any kind can happen.
    StatementMembranePressure applied onReverse osmosis?
    ACellophane, semipermeablechamber 1, concentratedYes
    BPorous, lets sugar throughchamber 2, diluteNo
    CParchment paper, semipermeablechamber 1, concentratedYes
    DCellophane, semipermeablechamber 2, diluteNo, this only speeds up normal osmosis
  3. So. Only A and C meet both conditions, so the answer is (a).

The idea to keep. For reverse osmosis, check two things: a semipermeable membrane, and pressure greater than π on the more concentrated solution. Pressure on the dilute side only helps normal osmosis.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 150 times in JEE Main since 2020. This question is from 2025.