JEE Main 2023 · 24 January · morning · Single correct · +4 / −1

It is observed that characteristic X-ray spectra of elements show regularity. When frequency to the power "n" i.e. vⁿ of X-rays emitted is plotted against atomic number "Z", following graph is obtained.
The value of 'n' is :

JEE Main PYQ figure
  1. (a) 1
  2. (b) 1/2
  3. (c) 2
  4. (d) 3
Answer and solution

Answer (b) 1/2

Solution

Chemistry ma’am · 4 steps

This is Moseley's law: the square root of the X-ray frequency grows in a straight line with Z.

  1. Moseley's law. Moseley measured characteristic X-ray frequencies ν of many elements. He found that √ν, not ν itself, rises linearly with atomic number Z.

    √ν = a (Z - b)

  2. Read the constants. a is a proportionality constant and b is the screening constant. Because of b, the line does not pass through the origin. That matches the graph, where the line would meet the Z-axis at Z = b.
  3. Match the axes. The graph is a straight line of νⁿ against Z. Moseley's law gives a straight line for ν^(1/2) against Z, so n = 1/2.
  4. So. The value of n is 1/2, option (b).

The idea to keep. Moseley's law is √ν = a(Z - b). Plot √ν against Z for a straight line. Plotting ν itself gives a curve, because ν grows as (Z - b)².

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 170 times in JEE Main since 2020. This question is from 2023.