JEE Main 2020 · 2 September · evening · Single correct · +4 / −1

If you spill a chemical toilet cleaning liquid on your hand, your first aid would be

  1. (a) aqueous NaOH
  2. (b) aqueous NaHCO₃
  3. (c) aqueous NH₃
  4. (d) vinegar
Answer and solution

Answer (b) aqueous NaHCO₃

Solution

Chemistry ma’am · 3 steps

Toilet cleaners are acidic, so wash the acid off with a mild base that cannot hurt your skin.

  1. What is spilled. Chemical toilet cleaners contain an acid, usually hydrochloric acid. On the skin, that acid has to be neutralised by a base.
  2. Pick a gentle base. The base must be mild. A strong base burns the skin just as badly as the acid does.
    OptionNatureSafe on skin?
    NaOHstrong baseno, it is caustic and burns skin
    NaHCO₃weak baseyes, it neutralises the acid gently
    NH₃ (aq)base with pungent, irritating fumesno, it irritates skin, eyes and lungs
    vinegaracid (acetic acid)no, it adds more acid

    NaHCO₃ + HCl → NaCl + H₂O + CO₂ ↑

  3. So. Aqueous sodium bicarbonate, option (b), neutralises the acid and leaves only harmless salt, water and carbon dioxide.

The idea to keep. For an acid on the skin use a weak base like NaHCO₃. For an alkali on the skin use a weak acid like dilute acetic acid. Never treat a burn with a strong reagent.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 40 times in JEE Main since 2020. This question is from 2020.