JEE Main 2021 · 1 September · evening · Single correct · +4 / −1

In the given chemical reaction, colors of the Fe²⁺ and Fe³⁺ ions, are respectively :
5Fe²⁺ + MnO₄ - + 8H⁺ → Mn²⁺ + 4H₂O + 5Fe³⁺

  1. (a) Yellow, Orange
  2. (b) Yellow, Green
  3. (c) Green, Orange
  4. (d) Green, Yellow
Answer and solution

Answer (d) Green, Yellow

Solution

Chemistry ma’am · 3 steps

Iron(II) solutions look pale green and iron(III) solutions look yellow, so read the ions before and after.

  1. What changes. MnO₄⁻ in acid oxidises Fe²⁺ to Fe³⁺, and is itself reduced to Mn²⁺. Iron loses one electron, going from 3d⁶ to 3d⁵.
    IonConfigurationColour in water
    Fe²⁺3d⁶pale green
    Fe³⁺3d⁵yellow (yellowish brown)
    MnO₄⁻Mn in +7 statedeep purple
    Mn²⁺3d⁵almost colourless (very pale pink)
  2. Colour of the ions. Hydrated Fe²⁺ is pale green, as in a solution of FeSO₄. Hydrated Fe³⁺ is yellow, as in a solution of FeCl₃.
  3. So. In order, the colours are green for Fe²⁺ and yellow for Fe³⁺, which is option (d).

The idea to keep. Remember the iron pair: Fe²⁺ is green and Fe³⁺ is yellow. When the green turns yellow, iron has been oxidised.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 90 times in JEE Main since 2020. This question is from 2021.