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Purification & Characterisation of Organic Compounds formula sheet

Every formula in the Purification & Characterisation of Organic Compounds chapter for JEE Main, with one line on when it applies. Topic 1 is open to everyone; sign in free to read all 14 and download the PDF.

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How we count: 7× asked means 7 past JEE Main questions in the PrepWiser bank needed that formula, and "last" is the latest year one appeared. ★ marks formulas asked 8 or more times.

Crystallisation, sublimation, extraction

Crystallisation and sublimation
3× asked, last 2023
crystallisation: soluble hot, sparingly coldsublimation: solid→vapour→solid\begin{aligned}&\text{crystallisation: soluble hot, sparingly cold}\\&\text{sublimation: solid}\to\text{vapour}\to\text{solid}\end{aligned}
Charcoal removes colour. Naphthalene, camphor sublime. Benzoic acid + naphthalene (both sublime): hot water.
Differential extraction
4× asked, last 2024
compound in water→immiscible solvent, shakeorganic layer\text{compound in water}\xrightarrow{\text{immiscible solvent, shake}}\text{organic layer}
Solvent dissolves the compound better; layers split in a separating funnel. Pure: sharp m.p., one TLC spot.

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Practise Purification & Characterisation of Organic Compounds

12 more formulas in 4 topics

Distillation, Chromatography, Lassaigne's test and Quantitative estimation. Read the first part free. Sign in free with Google to read the rest and download the PDF.

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Distillation

  • Simple distillation4×
  • Fractional and reduced-pressure4×
  • Steam distillation4×

Chromatography

  • Retardation factor6×
  • Polarity and elution6×

Lassaigne's test

  • Sodium fusion2×
  • Tests on the extract2×

Quantitative estimation

  • Carbon and hydrogen (Liebig)8×
  • Nitrogen: Dumas2×
  • Nitrogen: Kjeldahl3×
  • Halogens: Carius5×
  • Sulphur and phosphorus2×

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