JEE Main 2023 · 11 April · morning · Single correct · +4 / −1

Thin layer chromatography of a mixture shows the following observation:
The correct order of elution in the silica gel column chromatography is

JEE Main PYQ figure
  1. (a) B, A, C
  2. (b) C, A, B
  3. (c) A, C, B
  4. (d) B, C, A
Answer and solution

Answer (c) A, C, B

Solution

Chemistry ma’am · 3 steps

The spot that climbs highest on the TLC plate is the one that runs out of the column first.

  1. Read the plate. The line near the bottom is the baseline where the mixture was spotted. Judge each compound by where its dot sits, not its letter. A is highest, C is a little lower, and B is just above the baseline. So the order of R_f values is A > C > B.
  2. Same adsorbent. Both TLC and this column use silica gel, which is polar. A compound that is weakly adsorbed moves fast. It travels far up the plate (high R_f) and also leaves the column early. A strongly adsorbed compound lags behind in both.
    CompoundPosition on plateHold by silicaLeaves the column
    Ahighest, largest R_fweakestfirst
    Ca little below Amoderatesecond
    Bjust above the baseline, smallest R_fstrongestlast
  3. So. The order of elution from the silica gel column is A, C, B, which is option (c).

The idea to keep. On the same adsorbent, higher R_f means weaker adsorption, and that compound elutes first. So the elution order is the order of the spots from the top of the plate down.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Purification & Characterisation of Organic Compounds

Asked about 130 times in JEE Main since 2020. This question is from 2023.