JEE Main 2020 · 9 January · morning · Single correct · +4 / −1

The acidic, basic and amphoteric oxides, respectively, are :

  1. (a) Cl₂O, CaO, P₄O₁₀
  2. (b) N₂O₃, Li₂O, Al₂O₃
  3. (c) MgO, Cl₂O, Al₂O₃
  4. (d) Na₂O, SO₃, Al₂O₃
Answer and solution

Answer (b) N₂O₃, Li₂O, Al₂O₃

Solution

Chemistry ma’am · 3 steps

Sort each oxide by its element: non-metal gives acid, active metal gives base, and Al sits in between.

  1. The rule. A highly electronegative non-metal forms an acidic oxide, and an electropositive s-block metal forms a basic oxide. Borderline elements like Al, Be and Zn form amphoteric oxides that react with both acids and bases.
  2. Check option (b). N₂O₃ + H₂O → 2HNO₂ gives an acid. Li₂O + H₂O → 2LiOH gives a base. Al₂O₃ dissolves in both HCl and NaOH, so it is amphoteric.
    OptionFirst (should be acidic)Second (should be basic)Third (should be amphoteric)
    (a)Cl₂O: acidic, correctCaO: basic, correctP₄O₁₀: acidic, wrong
    (b)N₂O₃: acidic, correctLi₂O: basic, correctAl₂O₃: amphoteric, correct
    (c)MgO: basic, wrongCl₂O: acidic, wrongAl₂O₃: amphoteric, correct
    (d)Na₂O: basic, wrongSO₃: acidic, wrongAl₂O₃: amphoteric, correct
  3. So. Only (b) puts all three oxides in the right order: N₂O₃ acidic, Li₂O basic and Al₂O₃ amphoteric.

The idea to keep. The more electronegative the element, the more acidic its oxide. Non-metal oxides are acidic, s-block metal oxides are basic, and borderline elements like Al, Be and Zn give amphoteric oxides.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 120 times in JEE Main since 2020. This question is from 2020.