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Periodic Table & Periodicity JEE Main PYQs PDF, 2020–2026

Periodic Table & Periodicity has 124 questions in JEE Main papers from 2020 to 2026, about 18 per year across all shifts. The free PDF has 122 of them, each with its answer. The most asked topic is Ionisation Enthalpy (43 questions), followed by Atomic and Ionic Radii (27) and Modern Periodic Law (27).

Asked in JEE Main
1242020–2026, all shifts
In this free PDF
122with answers
Asked in 2026
18Latest paper: 2026 Apr S2
Most asked topic
Ionisation Enthalpy43 Qs · 34% of the chapter
Difficulty mix
57% easy · 43% mediumof the questions in the PDF

Answer key includedNo loginPractise online

Source: official NTA JEE Main papers · Updated

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2 of this chapter's questions came back in a later paper (2021–2026). See the most repeated.

How often it's asked in JEE Main

Periodic Table & Periodicity had about 1.1 questions per shift in recent JEE Main papers (2024–26). Most asked topic: Ionisation Enthalpy. About 18 questions in the 2026 papers.

It came up in most 2024–26 shifts in our bank (about 49 shifts). Question types in 2020–2026: about 122 MCQs and about 2 numerical.

How many questions from Periodic Table & Periodicity in JEE Main, year by year

YearQuestionsPer shiftMCQNumerical
2026180.9171
2025211.1210
2024221.1211
2023130.5130
2022190.8190
2021160.6160
2020150.9150
2020–20261240.81222

Most asked Periodic Table & Periodicity topics, 2020–2026

TopicQuestions
Ionisation Enthalpy43
Atomic and Ionic Radii27
Modern Periodic Law27
Electron Gain Enthalpy15
Anomalous Behaviour and Diagonal Relationship6

Every topic, year by year, is in the topic-wise table further down.

Counted from PrepWiser's question bank of JEE Main papers, 2020–2026. Per shift = questions that year ÷ shifts in our bank. Updated .

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Two free sheets, made from the past JEE Main questions on this chapter.

Watch: Periodic Table & Periodicity complete chapter (animated)

Periodic Table: Complete Chapter (Animated) | Class 11 Chemistry Ch 3 | JEE Main 2027

Periodic Table and periodicity complete chapter, animated, for JEE Main 2027 and Class 11 Chemistry (NCERT Ch 3). s, p, d and f blocks, atomic and ionic radius, ionisation enthalpy, electron gain enthalpy, electronegativity and the exceptions that JEE loves to ask.

Key moments

  1. 0:00The gallium puzzle
  2. 1:10Why a periodic table
  3. 3:53s, p, d and f blocks
  4. 6:14Atomic radius
  5. 8:24Ionic radius
  6. 10:09Ionization enthalpy
  7. 11:56Electron gain enthalpy
  8. 13:34Electronegativity
  9. 15:07Exceptions + one-screen summary
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Periodic Table & Periodicity questions per year

YearAskedIn PDF
20261818
20252121
20242221
20231312
20221919
20211616
20201515

in the free PDF asked, not in the PDFThe PDF only has questions we can print in full with a checked answer, so it holds 122 of the 124 asked.

Topic-wise weightage by year

How many Periodic Table & Periodicity questions each topic had in every JEE Main year (all shifts), counting every question asked, including ones not in the PDF. Darker cells mean more questions.

TopicAskedShare2026202520242023202220212020
Ionisation Enthalpy4334%10765564
Atomic and Ionic Radii2722%1651455
Modern Periodic Law2722%7533522
Electron Gain Enthalpy1512%·143322
Anomalous Behaviour and Diagonal Relationship65%··2·211
Electronegativity65%·221··1
All topics124100%18212213191615

Swipe the table sideways for older years.

Newest questions (2026)

The 12 newest of the 18 JEE Main 2026 Periodic Table & Periodicity questions in the free PDF, latest shift first.

  1. JEE Main 2026 · 8 Apr · Shift 2 · Ionisation Enthalpy

    Match List - I with List - II.\text{ Match List - I with List - II.}

    List - I
    Electronic configuration of neutral atom (where n=2n=2 )
    List - II
    1st1^{{\text{st}}} Ionization Energy ( kJ mol−1{\mathbf{k}\mathbf{J}\ \mathbf{m}\mathbf{o}\mathbf{l}}^{{-{\mathbf{1}}}} )
    A. ns2{\mathrm{ns}}^{2} I. 2080
    B. ns2np1{\mathrm{ns}}^{2}{\mathrm{np}}^{1} II. 899
    C. ns2np3ns^{2}np^{3} III. 800
    D. ns2np6ns^{2}np^{6} IV. 1402

    Choose the correct answer from the options given below :

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  2. JEE Main 2026 · 6 Apr · Shift 1 · Ionisation Enthalpy

    First and second ionization enthalpies of lithium are 520 kJ mol−1520{\ \mathrm{kJ}}{\ \mathrm{mol}}^{{-1}} and 7297 kJ mol−17297{\ \mathrm{kJ}}{\ \mathrm{mol}}^{{-1}} respectively. Energy required to convert 3.5 mg lithium (g) into Li2+(g)[Li(g)→Li2+(g)]{\mathrm{Li}}^{{2+}}({\mathrm{g}})\left[{\mathrm{Li}}({\mathrm{g}})\rightarrow {\mathrm{Li}}^{{2+}}({\mathrm{g}})\right] is ____\_\_\_\_ kJmol−1{\mathrm{kJ}}{\mathrm{mol}}^{{-1}}. (nearest integer)

    [Molar mass of Li=7 g mol−1{\mathrm{Li}}=7{\ \mathrm{g}}{\ \mathrm{mol}}^{{-1}} ]

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  3. JEE Main 2026 · 6 Apr · Shift 2 · Modern Periodic Law

    In a period, the first ionisation enthalpy of the element at extreme left and the negative electron gain enthalpy of the extreme right element, except noble gases, are respectively.

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  4. JEE Main 2026 · 5 Apr · Shift 2 · Ionisation Enthalpy

    Given below are two statements :

    Statement I : The number of pairs among [Al2O3,Cr2O3],[Cl2O7,Mn2O7],[Na2O,V2O3][{\mathrm{Al}}_{2}{\mathrm{O}}_{3},{\mathrm{Cr}}_{2}{\mathrm{O}}_{3}],[{\mathrm{Cl}}_{2}{\mathrm{O}}_{7},{\mathrm{Mn}}_{2}{\mathrm{O}}_{7}],[{\mathrm{Na}}_{2}{\mathrm{O}},{\mathrm{V}}_{2}{\mathrm{O}}_{3}] and [CO,N2O][{\mathrm{CO}},{\mathrm{N}}_{2}{\mathrm{O}}] that contain oxides of same nature (acidic, basic, neutral or amphoteric) is 4 .

    Statement II : Among Na2O,Al2O3,CO{\mathrm{Na}}_{2}{\mathrm{O}},{\mathrm{Al}}_{2}{\mathrm{O}}_{3},{\mathrm{CO}} and Cl2O7{\mathrm{Cl}}_{2}{\mathrm{O}}_{7}, the most basic and acidic oxides are Na2O{\mathrm{Na}}_{2}{\mathrm{O}} and Cl2O7{\mathrm{Cl}}_{2}{\mathrm{O}}_{7}, respectively.

    In the light of the above statements, choose the correct answer from the options given below :

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  5. JEE Main 2026 · 5 Apr · Shift 1 · Ionisation Enthalpy

    Given below are two statements:

    Statement I: The correct order of electronegativity of fluorine, oxygen and nitrogen is F>O>N{\mathrm{F}}>{\mathrm{O}}>{\mathrm{N}}.

    Statement II: The oxidation state of oxygen in OF2{\mathrm{OF}}_{2} is +2 and in Na2O{\mathrm{Na}}_{2}{\mathrm{O}} is -2 .

    In the light of the above statements, choose the correct answer from the options given below

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  6. JEE Main 2026 · 4 Apr · Shift 2 · Ionisation Enthalpy

    The 1st1^{{\text{st}}} ionization enthalpy for Mg is +737 kJ/mol+737{\ \mathrm{kJ}}/{\mathrm{mol}}. The most probable estimated value of the 2nd2^{{\text{nd}}} ionization enthalpy of Mg is ____\_\_\_\_ .

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  7. JEE Main 2026 · 2 Apr · Shift 1 · Ionisation Enthalpy

    Given below are two statements :

    Statement (I) : The first ionisation enthalpy of the elements Na, Mg, Cl and Ar follows the order Na > Mg > Cl > Ar.

    Statement (II) : Among Ca, Al, Fe and B, the third ionisation enthalpy is very high for Ca.

    In the light of the above statements, choose the correct answer from the options given below :

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  8. JEE Main 2026 · 2 Apr · Shift 2 · Ionisation Enthalpy

    The correct set that contains all kinds (basic, acidic, amphoteric and neutral) of oxides is :

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  9. JEE Main 2026 · 28 Jan · Shift 2 · Modern Periodic Law

    Consider the elements N, P, O, S, Cl and F. The number of valence electrons present in the elements with most and least metallic character from the above list is respectively.

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  10. JEE Main 2026 · 28 Jan · Shift 1 · Atomic and Ionic Radii

    In period 4 of the periodic table, the elements with highest and lowest atomic radii are respectively.

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  11. JEE Main 2026 · 24 Jan · Shift 2 · Ionisation Enthalpy

    The correct order of C,N,O{\mathrm{C}},{\mathrm{N}},{\mathrm{O}} and F in terms of second ionisation potential is

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  12. JEE Main 2026 · 24 Jan · Shift 1 · Modern Periodic Law

    Given below are two statements :

    Statement I : K>Mg>Al>B{\mathrm{K}}>{\mathrm{Mg}}>{\mathrm{Al}}>{\mathrm{B}} is the correct order in terms of metallic character.

    Statement II : Atomic radius is always greater than the ionic radius for any element.

    In the light of the above statements, choose the correct answer from the options given below

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Practise the 2026 Periodic Table & Periodicity questions online

Sample questions from recent papers

JEE Main 2025 · 7 Apr · Shift 2 · Atomic and Ionic Radii

Choose the incorrect trend in the atomic radii (r) of the elements.

  1. (A)

    rRb < rCs

  2. (B)

    rAt < rCs

  3. (C)

    rBr < rK

  4. (D)

    rMg < rAl

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Answer: (D)

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JEE Main 2025 · 2 Apr · Shift 2 · Electronegativity

Electronic configuration of four elements A, B, C and D are given below :

(A) 1s22s22p31 s^2 2 s^2 2 p^3

(B) 1s22s22p41 s^2 2 s^2 2 p^4

(C) 1s22s22p51 s^2 2 s^2 2 p^5

(D) 1s22s22p21 s^2 2 s^2 2 p^2

Which of the following is the correct order of increasing electronegativity (Pauling's scale)?

  1. (A)D<A<B<C\mathrm{D}<\mathrm{A}<\mathrm{B}<\mathrm{C}
  2. (B) A<B<C<D\mathrm{A}<\mathrm{B}<\mathrm{C}<\mathrm{D}
  3. (C)A<C<B<D\mathrm{A}<\mathrm{C}<\mathrm{B}<\mathrm{D}
  4. (D)A<D<B<C\mathrm{A}<\mathrm{D}<\mathrm{B}<\mathrm{C}
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Answer: (A)

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JEE Main 2025 · 29 Jan · Shift 1 · Electron Gain Enthalpy

Given below are two statements :

Statement (I) : The radii of isoelectronic species increases in the order.

Mg2+ < Na+ < F−- < O2-

Statement (II) : The magnitude of electron gain enthalpy of halogen decreases in the order.

Cl > F > Br > I

In the light of the above statements, choose the most appropriate answer from the options given below :

  1. (A)

    Statement I is incorrect but Statement II is correct

  2. (B)

    Both Statement I and Statement II are correct

  3. (C)

    Statement I is correct but Statement II is incorrect

  4. (D)

    Both Statement I and Statement II are incorrect

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Answer: (B)

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JEE Main 2024 · 4 Apr · Shift 1 · Anomalous Behaviour and Diagonal Relationship

Number of elements from the following that CANNOT form compounds with valencies which match with their respective group valencies is ________. B, C, N, S, O, F, P, Al, Si

  1. (A)7
  2. (B)3
  3. (C)5
  4. (D)6
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Answer: (B)

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Frequently asked

How many questions come from Periodic Table & Periodicity in JEE Main?

124 questions from 2020 to 2026, about 18 per year. In 2026 it had 18. The free PDF has 122 of them.

Which Periodic Table & Periodicity topics are most important for JEE Main?

By past papers: Ionisation Enthalpy (34%), Atomic and Ionic Radii (22%) and Modern Periodic Law (22%) of all Periodic Table & Periodicity questions.

Is the Periodic Table & Periodicity PYQ PDF free?

Yes. The PDF and its answer key are free, and you can practise the questions online with no login, with step-by-step solutions where available.

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JEE Main PYQs by year: 2026 · 2025 · 2024 · 2023 · 2022 · 2021 · 2020

Answers follow NTA's final answer keys. Typing errors are possible, so check doubtful answers against the official key. Spotted a mistake? prepwiser.in/feedback · Terms: prepwiser.in/terms