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Periodic Table & Periodicity JEE Main PYQs, 2020 to 2025

Periodic Table & Periodicity has 92 questions in JEE Main papers from 2020 to 2025, about 15 per year across all shifts. The most asked topic is Ionisation Enthalpy (30 questions), followed by Atomic and Ionic Radii (22) and Modern Periodic Law (15).

Updated

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92Total PYQs
6Years covered
6Topics
2025 Apr S2Latest paper

Periodic Table & Periodicity questions per year

YearQuestions
202517
202420
202310
202214
202116
202015

Topic-wise weightage

TopicQuestionsShare of chapterLast asked
Ionisation Enthalpy3033%2025
Atomic and Ionic Radii2224%2025
Modern Periodic Law1516%2025
Electron Gain Enthalpy1415%2025
Electronegativity67%2025
Anomalous Behaviour and Diagonal Relationship55%2024

Sample questions from recent papers

JEE Main 2025 · 8 Apr · Shift 2 · Ionisation Enthalpy

The atomic number of the element from the following with lowest 1st ionisation enthalpy is :

  1. (A)

    32

  2. (B)

    35

  3. (C)

    19

  4. (D)

    87

Answer: (D)

Step-by-step solution

JEE Main 2025 · 7 Apr · Shift 2 · Atomic and Ionic Radii

Choose the incorrect trend in the atomic radii (r) of the elements.

  1. (A)

    rRb < rCs

  2. (B)

    rAt < rCs

  3. (C)

    rBr < rK

  4. (D)

    rMg < rAl

Answer: (D)

Step-by-step solution

JEE Main 2025 · 2 Apr · Shift 2 · Electronegativity

Electronic configuration of four elements A, B, C and D are given below :

(A) 1s22s22p31 s^2 2 s^2 2 p^3

(B) 1s22s22p41 s^2 2 s^2 2 p^4

(C) 1s22s22p51 s^2 2 s^2 2 p^5

(D) 1s22s22p21 s^2 2 s^2 2 p^2

Which of the following is the correct order of increasing electronegativity (Pauling's scale)?

  1. (A)D<A<B<C\mathrm{D}<\mathrm{A}<\mathrm{B}<\mathrm{C}
  2. (B) A<B<C<D\mathrm{A}<\mathrm{B}<\mathrm{C}<\mathrm{D}
  3. (C)A<C<B<D\mathrm{A}<\mathrm{C}<\mathrm{B}<\mathrm{D}
  4. (D)A<D<B<C\mathrm{A}<\mathrm{D}<\mathrm{B}<\mathrm{C}

Answer: (A)

Step-by-step solution

JEE Main 2025 · 29 Jan · Shift 1 · Electron Gain Enthalpy

Given below are two statements :

Statement (I) : The radii of isoelectronic species increases in the order.

Mg2+ < Na+ < F−- < O2-

Statement (II) : The magnitude of electron gain enthalpy of halogen decreases in the order.

Cl > F > Br > I

In the light of the above statements, choose the most appropriate answer from the options given below :

  1. (A)

    Statement I is incorrect but Statement II is correct

  2. (B)

    Both Statement I and Statement II are correct

  3. (C)

    Statement I is correct but Statement II is incorrect

  4. (D)

    Both Statement I and Statement II are incorrect

Answer: (B)

Step-by-step solution

JEE Main 2025 · 28 Jan · Shift 2 · Modern Periodic Law

Given below are two statements :

Statement I : According to the Law of Octaves, the elements were arranged in the increasing order of their atomic number.

Statement II : Meyer observed a periodically repeated pattern upon plotting physical properties of certain elements against their respective atomic numbers.

In the light of the above statements, choose the correct answer from the options given below :

  1. (A)

    Both Statement I and Statement II are false

  2. (B)

    Statement I is false but Statement II is true

  3. (C)

    Statement I is true but Statement II is false

  4. (D)

    Both Statement I and Statement II are true

Answer: (A)

Step-by-step solution

JEE Main 2024 · 4 Apr · Shift 1 · Anomalous Behaviour and Diagonal Relationship

Number of elements from the following that CANNOT form compounds with valencies which match with their respective group valencies is ________. B, C, N, S, O, F, P, Al, Si

  1. (A)7
  2. (B)3
  3. (C)5
  4. (D)6

Answer: (B)

Step-by-step solution

All 92 questions are in the free PDF above, grouped by topic.

Frequently asked

How many questions come from Periodic Table & Periodicity in JEE Main?

92 questions from 2020 to 2025, about 15 per year. In 2025 it had 17.

Which Periodic Table & Periodicity topics are most important for JEE Main?

By past papers: Ionisation Enthalpy (33%), Atomic and Ionic Radii (24%) and Modern Periodic Law (16%) of all Periodic Table & Periodicity questions.

Is the Periodic Table & Periodicity PYQ PDF free?

Yes. The PDF, the answer key and every step-by-step solution on PrepWiser are free, with no login needed to practise.

More Chemistry chapters

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