JEE Main 2020 · 4 September · evening · Single correct · +4 / −1

The process that is NOT endothermic in nature is :

  1. (a) Ar(g) + e⁻ → Ar⁻(g)
  2. (b) H(g) + e⁻ → H⁻(g)
  3. (c) Na(g) → Na⁺(g) + e⁻
  4. (d) O⁻(g) + e⁻ → O²⁻(g)
Answer and solution

Answer (b) H(g) + e⁻ → H⁻(g)

Solution

Chemistry ma’am · 2 steps

Ask one thing of each process: does the particle actually want this electron change, or must you force it?

  1. What decides it. A process releases energy (exothermic) only when the product is more stable than the starting particle. Removing an electron always needs energy. Adding one releases energy only if the atom has room for it and nothing pushes it away.
    ProcessWhat happensEnergy change
    (a) Ar(g) + e⁻ → Ar-(g)Ar has a full octet, so the electron must go into a new, higher shellabout +96 kJ mol⁻¹, endothermic
    (b) H(g) + e⁻ → H-(g)The electron fills the 1s orbital and gives the stable 1s² configurationabout -73 kJ mol⁻¹, exothermic
    (c) Na(g) → Na⁺(g) + e⁻Ionisation: the nucleus still holds the 3s electron, so pulling it off costs energyabout +496 kJ mol⁻¹, endothermic
    (d) O-(g) + e⁻ → O²⁻(g)The incoming electron is repelled by the negative charge on O⁻about +780 kJ mol⁻¹, endothermic
  2. So. Three of the processes absorb energy. Only (b), adding an electron to a hydrogen atom, releases energy, so it is the one that is not endothermic.

The idea to keep. Ionisation is always endothermic. Adding an electron is endothermic for noble gases and for any anion, and exothermic for most neutral atoms with a vacancy, like H or the halogens.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Chemical Thermodynamics

Asked about 160 times in JEE Main since 2020. This question is from 2020.