JEE Main 2021 · 22 July · evening · Numerical answer · +4 / −0

If the standard molar enthalpy change for combustion of graphite powder is -2.48 × 10² kJ mol⁻¹, the amount of heat generated on combustion of 1 g of graphite powder is ___________ kJ. (Nearest integer)

Answer and solution

Answer 21

Solution

Chemistry ma’am · 3 steps

The enthalpy is given per mole, so first turn 1 g of graphite into moles and then scale the heat.

  1. Moles of graphite. Graphite is pure carbon, with molar mass 12 g mol⁻¹. So 1 g of graphite is 1/12 mol.
  2. Heat per mole. Burning 1 mol of graphite gives Δ_c H° = -2.48 × 10² = -248 kJ mol⁻¹. The minus sign means heat is released, so 248 kJ is given out per mole.

    q = 1/12 mol × 248 kJ mol⁻¹ = 20.67 kJ

  3. So. Burning 1 g of graphite generates about 20.67 kJ of heat, which rounds to 21.

The common slip: 248. Using the molar value directly, without converting 1 g to 1/12 mol, gives 248, not 21.

The idea to keep. Molar enthalpy is heat per mole. For a given mass, find the moles first, then multiply by the magnitude of Δ H; the sign only tells you heat is released.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Chemical Thermodynamics

Asked about 160 times in JEE Main since 2020. This question is from 2021.