JEE Main 2021 · 20 July · morning · Single correct · +4 / −1
Consider a mixture of gas molecule of types A, B and C having masses m A < m B < m C . The ratio of their root mean square speeds at normal temperature and pressure is :
- (a) v_A = v_B ≠ v_C
- (b) 1/v_A > 1/v_B > 1/v_C
- (c) 1/v_A < 1/v_B < 1/v_C
- (d) v_A = v_B = v_C = 0
Answer and solution
Answer (c) 1/v_A < 1/v_B < 1/v_C
Solution
Physics sir · 4 steps
Same temperature means same average kinetic energy, so the lighter molecule has to move faster.
- Shared temperature. In a mixture every gas is at the same temperature T. The rms speed depends only on T and the mass of one molecule.
vᵣₘₛ = √(3kT/m) ⇒ vᵣₘₛ ∝ 1/√m
- Order the speeds. Since m_A < m_B < m_C, the speeds run the other way: v_A > v_B > v_C. Each speed is nonzero and different, because the masses differ.
- Flip to reciprocals. Taking reciprocals of positive numbers reverses the inequality. So 1/v_A < 1/v_B < 1/v_C.
- So. The correct ordering is option (c).
The idea to keep. At a fixed temperature, vᵣₘₛ ∝ 1/√m: lighter means faster. When an option uses reciprocals, flip the inequality before you match it.
Answer from the NTA final answer key. Solution by PrepWiser.