JEE Main 2021 · 18 March · evening · Single correct · +4 / −1

Consider a sample of oxygen behaving like an ideal gas. At 300 K, the ratio of root mean square (rms) velocity to the average velocity of gas molecule would be :
(Molecular weight of oxygen is 32g/mol; R = 8.3 J K⁻¹ mol⁻¹)

  1. (a) √(3π/8)
  2. (b) √(3/3)
  3. (c) √(8/3)
  4. (d) √(8π/3)
Answer and solution

Answer (a) √(3π/8)

Solution

Physics sir · 4 steps

Both speeds have the same √(RT/M), so divide them and only the numbers in front survive.

  1. Write both speeds. For an ideal gas, vᵣₘₛ = √(3RT/M) and v_(avg) = √(8RT/(π M)).

    vᵣₘₛ/v_(avg) = √((3RT/M)/(8RT/(π M))) = √(3π/8)

  2. Data not needed. R, T and M cancel completely. The ratio is the same for every ideal gas at every temperature, so the 300 K, 32 g/mol and 8.3 are only there to distract you.
  3. Quick check. √(3π/8) ≈ √1.18 ≈ 1.09. That is just above 1, as expected, because the rms speed is always slightly larger than the average speed.
  4. So. The ratio is √(3π/8), option (a).

The idea to keep. Remember vᵣₘₛ : v_(avg) : vₘₚ = √3 : √(8/π) : √2. Any ratio of these speeds is a pure number, independent of gas and temperature.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Kinetic Theory of Gases

Asked about 130 times in JEE Main since 2020. This question is from 2021.