JEE Main 2021 · 26 August · morning · Single correct · +4 / −1

What are the products formed in sequence when excess of CO₂ is passed in slaked lime?

  1. (a) Ca(HCO₃)₂, CaCO₃
  2. (b) CaCO₃, Ca(HCO₃)₂
  3. (c) CaO, Ca(HCO₃)₂
  4. (d) CaO, CaCO₃
Answer and solution

Answer (b) CaCO₃, Ca(HCO₃)₂

Solution

Chemistry ma’am · 3 steps

First the milky carbonate forms, then extra CO₂ dissolves it as bicarbonate, so watch the order.

  1. First portion. Slaked lime is Ca(OH)₂. A little CO₂ turns it into insoluble calcium carbonate, which is why lime water turns milky.

    Ca(OH)₂ + CO₂ → CaCO₃ v + H₂O

  2. Excess CO2. More CO₂ reacts with this carbonate and water to give calcium hydrogencarbonate, CaCO₃ + CO₂ + H₂O → Ca(HCO₃)₂. It is soluble, so the milkiness disappears.
  3. So. The sequence is CaCO₃ first, then Ca(HCO₃)₂. That is option (b).

The idea to keep. Lime water plus CO₂: milky from CaCO₃, then clear again with excess as soluble Ca(HCO₃)₂. Bicarbonate can only form from carbonate that already exists.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 130 times in JEE Main since 2020. This question is from 2021.