JEE Main 2021 · 26 August · morning · Single correct · +4 / −1
What are the products formed in sequence when excess of CO₂ is passed in slaked lime?
- (a) Ca(HCO₃)₂, CaCO₃
- (b) CaCO₃, Ca(HCO₃)₂
- (c) CaO, Ca(HCO₃)₂
- (d) CaO, CaCO₃
Answer and solution
Answer (b) CaCO₃, Ca(HCO₃)₂
Solution
Chemistry ma’am · 3 steps
First the milky carbonate forms, then extra CO₂ dissolves it as bicarbonate, so watch the order.
- First portion. Slaked lime is Ca(OH)₂. A little CO₂ turns it into insoluble calcium carbonate, which is why lime water turns milky.
Ca(OH)₂ + CO₂ → CaCO₃ v + H₂O
- Excess CO2. More CO₂ reacts with this carbonate and water to give calcium hydrogencarbonate, CaCO₃ + CO₂ + H₂O → Ca(HCO₃)₂. It is soluble, so the milkiness disappears.
- So. The sequence is CaCO₃ first, then Ca(HCO₃)₂. That is option (b).
The idea to keep. Lime water plus CO₂: milky from CaCO₃, then clear again with excess as soluble Ca(HCO₃)₂. Bicarbonate can only form from carbonate that already exists.
Answer from the NTA final answer key. Solution by PrepWiser.