JEE Main 2023 · 10 April · morning · Single correct · +4 / −1

Lime reacts exothermally with water to give 'A' which has low solubility in water. Aqueous solution of 'A' is often used for the test of CO₂, a test in which insoluble B is formed. If B is further reacted with CO₂ then soluble compound is formed, 'A' is :

  1. (a) Quick lime
  2. (b) White lime
  3. (c) Lime water
  4. (d) Slaked lime
Answer and solution

Answer (d) Slaked lime

Solution

Chemistry ma’am · 4 steps

Lime plus water is slaking, so 'A' is slaked lime. Its clear solution in water is what we call lime water.

  1. Slaking lime. Lime (quick lime) is CaO. It reacts with water and gives out a lot of heat, forming calcium hydroxide, which is only sparingly soluble in water.

    CaO + H₂O → Ca(OH)₂ (exothermic)

  2. Test for CO2. A clear solution of Ca(OH)₂ (lime water) turns milky with CO₂ because insoluble CaCO₃ forms: Ca(OH)₂ + CO₂ → CaCO₃ v + H₂O. So B is CaCO₃.
  3. Excess CO2. With more CO₂ the milkiness disappears, because soluble calcium hydrogencarbonate forms: CaCO₃ + CO₂ + H₂O → Ca(HCO₃)₂. Every clue fits Ca(OH)₂ as A.
  4. So. 'A' is Ca(OH)₂, the compound named slaked lime, option (d).

The idea to keep. Keep the lime family straight: CaO is quick lime, Ca(OH)₂ is slaked lime, and its clear aqueous solution is lime water. Milky with CO₂, clear again with excess CO₂.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 130 times in JEE Main since 2020. This question is from 2023.