JEE Main 2023 · 8 April · morning · Single correct · +4 / −1

What is the purpose of adding gypsum to cement?

  1. (a) To facilitate the hydration of cement
  2. (b) To speed up the process of setting
  3. (c) To give a hard mass
  4. (d) To slow down the process of setting
Answer and solution

Answer (d) To slow down the process of setting

Solution

Chemistry ma’am · 4 steps

Gypsum is the brake in cement: it stops the aluminate from setting the paste before you can use it.

  1. The fast culprit. Cement clinker contains tricalcium aluminate, 3CaO.Al₂O₃. It reacts with water very quickly, so without help the paste would harden within minutes. This is called flash setting.
  2. What gypsum does. About 2 to 3% gypsum, CaSO₄.2H₂O, is ground in with the clinker. It reacts with the aluminate to form calcium sulphoaluminate, which coats the aluminate grains and slows down their reaction with water.
  3. Why that helps. With setting delayed, there is enough time to mix, carry and lay the concrete. The slower silicate hydration then gives the final strength.
  4. So. Gypsum is added to slow down the process of setting, which is option (d).

The idea to keep. In cement, gypsum is a retarder. Remember the pair: the aluminate sets too fast, and gypsum calms it down. The strength comes later from the silicates.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 130 times in JEE Main since 2020. This question is from 2023.