True or false · +4 / −1
E2 reactions are bimolecular and show anti-elimination.
Answer and solution
Answer: true
Solution
Chemistry ma’am · 4 steps
Both halves are true: the base and the substrate meet in one step, and H and X leave from opposite faces.
- One concerted step. In E2 the base pulls off the β-hydrogen while the C–X bond breaks and the C=C bond forms, all in a single step. No intermediate is formed.
Rate = k [R–X] [Base]
- Why bimolecular. Two species, the substrate and the base, take part in that slow step. So the rate depends on both concentrations, and the reaction is second order and bimolecular.
- Why anti. The β-H and the leaving group X must lie in one plane on opposite sides of the C–C bond (anti-periplanar, dihedral angle 180°). Only then do the C–H and C–X orbitals line up to form the new π bond, and this staggered arrangement is also the most stable one.
- So. E2 is bimolecular and shows anti-elimination. The statement is true.
The idea to keep. E2 means one step with two partners, so rate = k[substrate][base]. Always look for an H that is anti-periplanar to the leaving group; in cyclohexanes both must be axial.
Answer from the NTA final answer key. Solution by PrepWiser.