JEE Main 2023 · 10 April · evening · Single correct · +4 / −1

The correct order of metallic character is :

  1. (a) K > Be > Ca
  2. (b) Ca > K > Be
  3. (c) K > Ca > Be
  4. (d) Be > Ca > K
Answer and solution

Answer (c) K > Ca > Be

Solution

Chemistry ma’am · 4 steps

Metallic character means losing electrons easily, so rank by how low the ionisation enthalpy is.

  1. What to compare. A metal is an element that gives away its valence electrons easily. The lower the ionisation enthalpy, the more metallic the element.
    ElementPositionFirst ionisation enthalpyMetallic character
    KGroup 1, period 4419 kJ mol⁻¹highest
    CaGroup 2, period 4590 kJ mol⁻¹middle
    BeGroup 2, period 2899 kJ mol⁻¹lowest
  2. K versus Ca. Both are in period 4. Calcium has one more proton pulling on the same 4s shell, so its electrons are held more tightly. Potassium also has to lose only one electron to reach a noble gas configuration, so K is more metallic.
  3. Ca versus Be. Both are in group 2. Beryllium is two periods higher, so its 2s electrons sit much closer to the nucleus and are hard to remove. Be is the least metallic of the three.
  4. So. The order is K > Ca > Be, which is option (c).

The idea to keep. Metallic character rises down a group and falls across a period from left to right. It runs exactly opposite to ionisation enthalpy.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 120 times in JEE Main since 2020. This question is from 2023.