JEE Main 2020 · 7 January · morning · Single correct · +4 / −1

The number of orbitals associated with quantum number n = 5, mₛ = +1/2 is :

  1. (a) 11
  2. (b) 25
  3. (c) 15
  4. (d) 50
Answer and solution

Answer (b) 25

Solution

Chemistry ma’am · 3 steps

Spin adds no orbitals: count the orbitals in shell 5, and each holds one +1/2 electron.

  1. Count the subshells. For n = 5, l runs from 0 to n - 1 = 4. That gives the 5s, 5p, 5d, 5f and 5g subshells, and each holds 2l + 1 orbitals.

    1 + 3 + 5 + 7 + 9 = 25 = n²

  2. Role of spin. Spin mₛ describes an electron inside an orbital. It does not add orbitals. Every one of the 25 orbitals can hold exactly one electron with mₛ = +1/2.
  3. So. All n² = 25 orbitals qualify. That is also the number of electrons with mₛ = +1/2, so the answer is (b).

The idea to keep. A shell has n² orbitals and 2n² electrons. Fixing mₛ halves the electron count, but the number of orbitals stays n².

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 170 times in JEE Main since 2020. This question is from 2020.