JEE Main 2023 · 29 January · morning · Single correct · +4 / −1

During the borax bead test with CuSO₄, a blue green colour of the bead was observed in oxidising flame due to the formation of :

  1. (a) CuO
  2. (b) Cu(BO₂)₂
  3. (c) Cu₃B₂
  4. (d) Cu
Answer and solution

Answer (b) Cu(BO₂)₂

Solution

Chemistry ma’am · 4 steps

The bead's colour comes from a metaborate, so ask what CuO becomes once it meets B₂O₃.

  1. Make the bead. On heating, borax loses its water and then breaks down into sodium metaborate and boric anhydride. The B₂O₃ part is the glassy acidic oxide that reacts with the metal.

    Na₂B₄O₇ →(Δ) 2NaBO₂ + B₂O₃

  2. Copper salt reacts. In the flame CuSO₄ first gives CuO. The basic CuO then combines with acidic B₂O₃ to give copper(II) metaborate: CuO + B₂O₃ → Cu(BO₂)₂.
  3. Oxidising flame. The oxidising flame keeps copper in the +2 state. The Cu²⁺ ion inside the glassy bead gives the blue green colour.
  4. So. The blue green bead is due to Cu(BO₂)₂, option (b).

The idea to keep. In the borax bead test, the colour in the oxidising flame always comes from the metal metaborate, M(BO₂)₂. The reducing flame lowers the metal's oxidation state and changes the colour.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Qualitative Analysis — Salt Analysis

Asked about 80 times in JEE Main since 2020. This question is from 2023.