JEE Main 2024 · 4 April · morning · Single correct · +4 / −1
The correct sequence of ligands in the order of decreasing field strength is :
- (a) NCS⁻>EDTA⁴⁻>CN⁻>CO
- (b) CO>H₂ O>F⁻>S²⁻
- (c) S²⁻> ⁻ OH>EDTA⁴⁻>CO
- (d) ⁻ OH>F⁻>NH₃>CN⁻
Answer and solution
Answer (b) CO>H₂ O>F⁻>S²⁻
Solution
Chemistry ma’am · 3 steps
Fix the ends of the series first: CO is the strongest, halides and sulphide sit at the weak end.
- Spectrochemical series. Ligands are ranked by how much they split the d orbitals, that is, by the size of Δₒ. Here is the order from weakest to strongest field.
I⁻ < Br⁻ < SCN⁻ < Cl⁻ < S²⁻ < F⁻ < OH⁻ < H₂O < NCS⁻ < EDTA⁴⁻ < NH₃ < en < CN⁻ < CO
- Why the ends. CO and CN⁻ accept electron density back from the metal through π bonding, so they give the largest splitting. Halides and S²⁻ donate extra π electrons, which shrinks the splitting, so they sit at the weak end.
Option Order given Direction it really runs (a) NCS⁻ > EDTA⁴⁻ > CN⁻ > CO weakest to strongest, so reversed (b) CO > H₂O > F⁻ > S²⁻ strongest to weakest, correct (c) S²⁻ > OH⁻ > EDTA⁴⁻ > CO weakest to strongest, so reversed (d) OH⁻ > F⁻ > NH₃ > CN⁻ puts the strongest, CN⁻, last, so wrong - So. Only (b) runs from the strongest ligand down to the weakest: CO > H₂O > F⁻ > S²⁻.
The idea to keep. Remember three zones: halides and S²⁻ weak, H₂O and NH₃ middle, CN⁻ and CO strongest. Then check which way each option runs.
Answer from the NTA final answer key. Solution by PrepWiser.