JEE Main 2024 · 4 April · morning · Single correct · +4 / −1

The correct sequence of ligands in the order of decreasing field strength is :

  1. (a) NCS⁻>EDTA⁴⁻>CN⁻>CO
  2. (b) CO>H₂ O>F⁻>S²⁻
  3. (c) S²⁻> ⁻ OH>EDTA⁴⁻>CO
  4. (d) ⁻ OH>F⁻>NH₃>CN⁻
Answer and solution

Answer (b) CO>H₂ O>F⁻>S²⁻

Solution

Chemistry ma’am · 3 steps

Fix the ends of the series first: CO is the strongest, halides and sulphide sit at the weak end.

  1. Spectrochemical series. Ligands are ranked by how much they split the d orbitals, that is, by the size of Δₒ. Here is the order from weakest to strongest field.

    I⁻ < Br⁻ < SCN⁻ < Cl⁻ < S²⁻ < F⁻ < OH⁻ < H₂O < NCS⁻ < EDTA⁴⁻ < NH₃ < en < CN⁻ < CO

  2. Why the ends. CO and CN⁻ accept electron density back from the metal through π bonding, so they give the largest splitting. Halides and S²⁻ donate extra π electrons, which shrinks the splitting, so they sit at the weak end.
    OptionOrder givenDirection it really runs
    (a)NCS⁻ > EDTA⁴⁻ > CN⁻ > COweakest to strongest, so reversed
    (b)CO > H₂O > F⁻ > S²⁻strongest to weakest, correct
    (c)S²⁻ > OH⁻ > EDTA⁴⁻ > COweakest to strongest, so reversed
    (d)OH⁻ > F⁻ > NH₃ > CN⁻puts the strongest, CN⁻, last, so wrong
  3. So. Only (b) runs from the strongest ligand down to the weakest: CO > H₂O > F⁻ > S²⁻.

The idea to keep. Remember three zones: halides and S²⁻ weak, H₂O and NH₃ middle, CN⁻ and CO strongest. Then check which way each option runs.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 250 times in JEE Main since 2020. This question is from 2024.