JEE Main 2024 · 5 April · morning · Single correct · +4 / −1

The correct order of ligands arranged in increasing field strength.

  1. (a) F⁻<Br⁻<I⁻<NH₃
  2. (b) H₂ O<⁻OH<CN⁻<NH₃
  3. (c) Br⁻<F⁻<H₂ O<NH₃
  4. (d) Cl⁻<⁻OH<Br⁻<CN⁻
Answer and solution

Answer (c) Br⁻<F⁻<H₂ O<NH₃

Solution

Chemistry ma’am · 3 steps

Write out the spectrochemical series once, then check every inequality in each option against it.

  1. The series. Field strength is how far a ligand splits the d orbitals (Δₒ). Experiment ranks ligands in the spectrochemical series, from weakest to strongest.

    I⁻ < Br⁻ < Cl⁻ < F⁻ < OH⁻ < H₂O < NH₃ < en < CN⁻ < CO

  2. Two patterns. Halides get weaker going down the group, so I⁻ is the weakest. Neutral H₂O is stronger than OH⁻, and CN⁻ is near the strong end, above NH₃.
    OptionWhere it goes wrongVerdict
    (a)Halides reversed: really I⁻ < Br⁻ < F⁻wrong
    (b)OH⁻ < H₂O, and CN⁻ is stronger than NH₃wrong
    (c)Br⁻ < F⁻ < H₂O < NH₃, every step matchescorrect
    (d)Br⁻ is weaker than both Cl⁻ and OH⁻wrong
  3. So. Only (c) follows the spectrochemical series at every step, so the answer is (c).

The idea to keep. Learn the spectrochemical series as anchors: halides at the weak end (I⁻ weakest), then OH⁻ < H₂O < NH₃ < en, with CN⁻ and CO at the strong end.

Answer from the NTA final answer key. Solution by PrepWiser.

Study Coordination Compounds

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