JEE Main 2024 · 9 April · morning · Single correct · +4 / −1

The molar conductivity for electrolytes A and B are plotted against C^(3 / 2) as shown below. Electrolytes A and B respectively are:

JEE Main PYQ figure
  1. (a) A - weak electrolyte B - weak electrolyte
  2. (b) A - weak electrolyte B - strong electrolyte
  3. (c) A - strong electrolyte B - strong electrolyte
  4. (d) A - strong electrolyte B - weak electrolyte
Answer and solution

Answer (b) A - weak electrolyte B - strong electrolyte

Solution

Chemistry ma’am · 3 steps

Look at the shape: a straight line against √C means strong, a sharp shoot-up on dilution means weak.

  1. Strong electrolyte. A strong electrolyte is fully ionised at every concentration. Λₘ falls only a little as C rises, because ions drag on each other more. That fall is linear in √C (the x-axis of the graph).

    Λₘ = Λₘ° - A√C

  2. Weak electrolyte. A weak electrolyte ionises more and more as it is diluted. So Λₘ stays low at higher concentration and rises very steeply as C → 0. The plot is a curve, not a line.
    PlotShape on the graphElectrolyte
    ACurve, rises sharply near C = 0weak
    BStraight line, gentle downward slopestrong
  3. So. A is a weak electrolyte and B is a strong electrolyte, which is option (b).

The idea to keep. In a Λₘ vs √C plot, a straight line you can extend back to the y-axis means strong. A steep curve that cannot be extended to give Λₘ° means weak.

Answer from the NTA final answer key. Solution by PrepWiser.

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Asked about 170 times in JEE Main since 2020. This question is from 2024.