JEE Main 2023 · 13 April · morning · Single correct · +4 / −1

The incorrect statement from the following for borazine is :

  1. (a) It can react with water.
  2. (b) It is a cyclic compound.
  3. (c) It has electronic delocalization.
  4. (d) It contains banana bonds.
Answer and solution

Answer (d) It contains banana bonds.

Solution

Chemistry ma’am · 3 steps

Borazine is inorganic benzene; banana bonds belong to its boron cousin diborane, not to borazine.

  1. Know the structure. Borazine, B₃N₃H₆, is a flat six-membered ring of alternating B and N atoms. Each B and each N carries one H, just as each C in benzene does.
  2. Source of delocalisation. Each N gives its lone pair into the empty p orbital of the neighbouring B. This spreads the π electrons around the ring, though less evenly than in benzene because N is more electronegative than B.
    StatementTrue for borazine?Reason
    (a) Reacts with waterYesWater attacks the polar B–N bonds: B₃N₃H₆ + 9H₂O → 3B(OH)₃ + 3NH₃ + 3H₂
    (b) CyclicYesA six-membered B–N ring, like benzene
    (c) Electronic delocalisationYesN lone pairs are shared into the empty p orbitals of B
    (d) Banana bondsNoEvery bond is a normal two-centre two-electron bond. The 3c–2e B–H–B banana bonds are found in B₂H₆
  3. So. Statements (a), (b) and (c) are all true. The incorrect statement is (d), because borazine has no banana bonds.

The idea to keep. Banana bonds (3c–2e B–H–B bridges) belong to diborane. Borazine is benzene-like: a cyclic, delocalised B–N ring, but more reactive than benzene because the B–N bond is polar.

Answer from the NTA final answer key. Solution by PrepWiser.

Study p-Block Elements — Part I (Group 13 & 14)

Asked about 60 times in JEE Main since 2020. This question is from 2023.